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Sigma-Aldrich

Manganese(II) acetate tetrahydrate

99.99% trace metals basis

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Synonym(s):
Manganous acetate
Linear Formula:
(CH3COO)2Mn · 4H2O
CAS Number:
6156-78-1
Molecular Weight:
245.09
Beilstein:
3730728
EC Number:
211-334-3
MDL number:
MFCD00062552
UNSPSC Code:
12352300
PubChem Substance ID:
24853745
NACRES:
NA.23

Quality Level

200

Assay

99.99% trace metals basis

form

crystalline powder

reaction suitability

core: manganese

mp

>300 °C (lit.)

density

1.589 g/mL at 25 °C (lit.)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Mn]OC(C)=O

InChI

1S/2C2H4O2.Mn.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2

InChI key

CESXSDZNZGSWSP-UHFFFAOYSA-L

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General description

Manganese(II) acetate tetrahydrate is an ionic compound soluble in water and polar solvents. It is commonly used as a precursor in chemical vapor deposition (CVD) processes to fabricate cathode materials for lithium-ion batteries. It is also used as a sol-gel precursor to synthesize manganese oxide-based catalysts and other functional materials. Additionally, manganese (II) acetate tetrahydrate serves as a mordant in dyeing, a drier for paints and varnishes, and an oxidation catalyst. It is employed in the production of high-purity manganese dioxide, manganese oxide hydrate, and other manganese-containing compounds.

Application

Manganese(ll) acetate tetrahydrate can be used as:     
  • A starting material in the synthesis of manganese carboxylates, which are used to prepare manganese oxide thin films by chemical vapor deposition (CVD).    
  • A precursor in the synthesis of manganese-TiO2 composites by chemical vapor condensation (CVC).These composites are used in the oxidation of NO at low temperatures.    
  • A precursor in preparation of NCM (LiNi1/3Co1/3Mn1/3O2) powder applicable as cathode material in lithium-ion batteries.

Pictograms

Health hazard
GHS08

Signal Word

Warning

Hazard Statements

H373,H412

Precautionary Statements

P260 - P273 - P314 - P501

Hazard Classifications

Aquatic Chronic 3 - STOT RE 2 Inhalation

Target Organs

Brain

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Renfa Liu et al.
Theranostics, 5(10), 1144-1153 (2015-08-19)
The integration of diagnostic and therapeutic functionalities into one nanoplatform shows great promise in cancer therapy. In this research, manganese (II) chelate functionalized copper sulfide nanoparticles were successfully prepared using a facile hydrothermal method. The obtained ultrasmall nanoparticles exhibit excellent
Kyu-Nam Jung et al.
Scientific reports, 5, 7665-7665 (2015-01-08)
Rechargeable metal-air batteries are considered a promising energy storage solution owing to their high theoretical energy density. The major obstacles to realising this technology include the slow kinetics of oxygen reduction and evolution on the cathode (air electrode) upon battery
Rusi et al.
PloS one, 10(7), e0129780-e0129780 (2015-07-15)
The composite metal oxide electrode films were fabricated using ex situ electrodeposition method with further heating treatment at 300°C. The obtained composite metal oxide film had a spherical structure with mass loading from 0.13 to 0.21 mg cm(-2). The structure
Qiangqiang Sun et al.
Journal of hazardous materials, 286, 276-284 (2015-01-16)
Comparative experiments were conducted to investigate the catalytic ability of MnO(x)/SBA-15 for the ozonation of clofibric acid (CA) and its reaction mechanism. Compared with ozonation alone, the degradation of CA was barely enhanced, while the removal of TOC was significantly

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