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229415

Sigma-Aldrich

Aluminum nitrate nonahydrate

99.997% trace metals basis

Synonym(s):

Aluminium nitrate

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About This Item

Linear Formula:
Al(NO3)3 · 9H2O
CAS Number:
7784-27-2
Molecular Weight:
375.13
EC Number:
236-751-8
MDL number:
MFCD00149132
UNSPSC Code:
12352302
PubChem Substance ID:
24853274
NACRES:
NA.23

Quality Level

200

Assay

99.997% trace metals basis

form

crystals and lumps

impurities

≤35.0 ppm Trace Metal Analysis

bp

135 °C (lit.)

mp

73 °C (lit.)

solubility

ethanol: very soluble(lit.)

application(s)

battery manufacturing

SMILES string

O.O.O.O.O.O.O.O.O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Al.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;

InChI key

SWCIQHXIXUMHKA-UHFFFAOYSA-N

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General description

Aluminum nitrate nonahydrate is a crystalline aluminum salt of nitric acid primarily used as a catalyst in manufacturing petroleum products, including gasoline and other fuels. It is also used in the production of aluminum oxide and the fabrication of cathode material for lithium-ion batteries.

Application

Aluminum nitrate nonahydrate can be used as a precursor to synthesize:
  • AlF3-coated LiCoO2, which is used to prepare a blend composite cathode with Li [Ni1/3Co1/3Mn1/3] O2 for Li-ion batteries.
  • Disperse alumina.
  • Alumina gel by sol-gel method and pure gamma alumina by hydrolysis.
  • Nanocrystalline ZnAl2O4 by hydrothermal method.
  • Magnesium aluminum layered hydroxides which are applicable as nanocontainers of corrosion inhibitors for protective organic coatings.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H318

Precautionary Statements

P280 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1

WGK

WGK 1

Flash Point(F)

does not flash

Flash Point(C)

does not flash

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Stefan Neatu et al.
Materials (Basel, Switzerland), 12(11) (2019-06-05)
This study presents the synthesis and characterization of lanthanum-modified alumina supported cerium-manganese mixed oxides, which were prepared by three different methods (coprecipitation, impregnation and citrate-based sol-gel method) followed by calcination at 500 °C. The physicochemical properties of the synthesized materials
Hydrothermal Synthesis of High Specific Capacity Al-doped V6O13 Cathode Material for Lithium-Ion Battery
Zhengguang Zou, et al.
International Journal of Electrochemical Science, 12, 1670-1679 (2017)
Fabrication of ?-alumina fibers by sol-gel and electrospinning of aluminum nitrate precursor solutions
Jose Hafid Roque-Ruiz, et al
Results in Physics, 12, 193-204 (2019)
Ivan F Myronyuk et al.
Nanoscale research letters, 11(1), 153-153 (2016-03-24)
Transformation of Al(NO3)3∙9H2O (upon heating in the range of 20-1200 °C) into blends of amorphous and crystalline boehmite (210-525 °C), amorphous alumina and crystalline γ-Al2O3 (850 °C), and crystalline α-Al2O3 (1100 °C) was analyzed using X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), infrared
AlF 3-coated LiCoO 2 and Li [Ni 1/3 Co 1/3 Mn 1/3] O 2 blend composite cathode for lithium ion batteries.
Lee KS, et al.
Journal of Power Sources, 196(16), 6974-6977 (2011)
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