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Silver hexafluorophosphate

Name: Silver hexafluorophosphate
Brand: ALDRICH

98%

Synonym(s):

Silver(I) hexafluorophosphate

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About This Item

Linear Formula:

AgPF₆

CAS Number:

26042-63-7

Molecular Weight:

252.83

EC Number:

247-428-6

MDL number:

MFCD00003415

UNSPSC Code:

12161600

PubChem Substance ID:

24853649

NACRES:

NA.22

Quality Level

100

Assay

98%

form

solid

reaction suitability

core: silver
reagent type: catalyst

mp

102 °C (dec.) (lit.)

SMILES string

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

InChI key

SCQBROMTFBBDHF-UHFFFAOYSA-N

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Related Categories

Inorganic Catalysts

Phosphates

Silver Compounds

Transition Metal Catalysts

General description

Silver hexafluorophosphate can be used as a catalyst for the sulfimidation, hydrogenation of aldehydes to alcohols, and hydroacyloxylation of alkynes with carboxylic acids.

Application

Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials. Preparation of supramolecular networks of Ag(I) complexes.

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Gold (I)-catalyzed addition of carboxylic acids to alkynes

Chary B, et al.

The Journal of Organic Chemistry, 75, 7928-7931 (2010)

Journal of Organometallic Chemistry, 692, 4093-4093 (2007)

Silver-Catalyzed Hydrogenation of Aldehydes in Water

Jia Z, et al.

Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)

Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions

Annapureddy R, et al.

Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)

Coordination Networks of 3,3'-Dicyanodiphenylacetylene and Silver(I) Salts: Structural Diversity through Changes in Ligand Conformation and Counterion.

Keith A. Hirsch et al.

Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)

Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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