All Photos(3)
2,4-Bis(4-methoxyphenyl)-2,4-dithioxo-1,3,2,4-dithiadiphosphetane, 2,4-Bis-(4-methoxyphenyl)-1,3-dithia-2,4-diphosphetane 2,4-disulfide, 4-Methoxyphenylthiophosphoric cyclic di(thioanhydride), LR
C14H14O2P2S4
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Quality Level
Assay
97%
form
powder
mp
228-230 °C (lit.)
SMILES string
COc1ccc(cc1)P2(=S)SP(=S)(S2)c3ccc(OC)cc3
InChI
1S/C14H14O2P2S4/c1-15-11-3-7-13(8-4-11)17(19)21-18(20,22-17)14-9-5-12(16-2)6-10-14/h3-10H,1-2H3
InChI key
CFHGBZLNZZVTAY-UHFFFAOYSA-N
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General description
Lawesson′s reagent is generally used as a thiation agent in organic synthesis for the conversion of oxygen functionalities into their thio analogs. It facilitates the conversion of the carbonyl group to thiocarbonyl group as well as carbon-oxygen single bond into a carbon-sulfur single bond.
Application
Lawesson reagent can be used as a reagent to synthesize:
- Oxthiaphosphinine-3-sulfide derivatives by the reaction with Mannich bases of β-naphthol and 8-hydroxyquinoline.
- 1,3,5,2-Trithiaphosphinane-2-sulfide derivatives by reacting with benzaldehyde in the presence of trialkyl phosphite.
- 2,4,6-Triphenyl-1,3,5-trithiane from benzaldehyde and ethyl acrylate.
- 9-Benzanthronethione by thionation of 9-benzanthone oxime.
- 1,2,4-Trithiolane from 2,2,4,4-tetramethyl-3-thioxocyclobutanone S-oxide.
- Sulfur derivatives of triterpenic oxo compounds.
- Tropothione in situ at room temperature and to trap it with dieneophiles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Water-react 2
Supplementary Hazards
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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A novel protocol for the generation of tropothione and its trapping with electron deficient dienophiles
Tetrahedron Letters, 47(52), 9329-9329 (2006)
Synthesis of 1, 2, 4-trithiolanes from thione S-oxides and Lawesson reagent at room temperature
Bulletin of the Chemical Society of Japan, 77(1), 187-188 (2004)
Journal of the American Chemical Society, 139(28), 9650-9661 (2017-06-20)
Symmetric molecular motors based on two overcrowded alkenes with a notable absence of a stereogenic center show potential to function as novel mechanical systems in the development of more advanced nanomachines offering controlled motion over surfaces. Elucidation of the key
Chemical communications (Cambridge, England), (2)(2), 206-208 (2005-12-24)
A one-pot reaction of maltol with Lawesson's reagent generates dithiomaltol, a thiopyran-4-thione, via an unusual heterocyclic atom exchange (HCAE) reaction; only pyrones with proton or aliphatic substituents undergo the HCAE substitution.
Nature genetics, 48(12), 1462-1472 (2016-11-01)
The genetic architecture of human reproductive behavior-age at first birth (AFB) and number of children ever born (NEB)-has a strong relationship with fitness, human development, infertility and risk of neuropsychiatric disorders. However, very few genetic loci have been identified, and
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