226289
N,N-Dimethyltrimethylsilylamine
97%
Synonym(s):
(Dimethylamino)trimethylsilane, N-(Trimethylsilyl)dimethylamine, TMSDMA
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About This Item
Product Name
N,N-Dimethyltrimethylsilylamine, 97%
InChI key
KAHVZNKZQFSBFW-UHFFFAOYSA-N
InChI
1S/C5H15NSi/c1-6(2)7(3,4)5/h1-5H3
SMILES string
CN(C)[Si](C)(C)C
assay
97%
form
liquid
refractive index
n20/D 1.397 (lit.)
bp
84 °C (lit.)
density
0.732 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
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Application
- Trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct, which is used as an efficient reagent for nucleophilic trifluoromethylation of carbonyl and the imine group.
- (Dimethylamino)sulfur trifluoride (Me-DAST), which is employed as a deoxofluorinating agent for the conversion of aliphatic alcohols into their corresponding fluorides.
- Nucleoside phosphoramidites by reacting with alkyloxy (or aryloxy)-triazolylphosphine and deoxynucleoside.
It can also be used as a silylating agent in chemical synthesis.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Articles
Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs
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