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Merck
CN

225460

Diironnonacarbonyl

98%, solid

Synonym(s):

Enneacarbonyldiiron, Iron enneacarbonyl, Nonacarbonyldiiron

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About This Item

Linear Formula:
Fe2(CO)9
CAS Number:
Molecular Weight:
363.78
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
239-359-5
MDL number:
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Product Name

Diironnonacarbonyl, 98%

InChI key

JCXLZXJCZPKTBW-UHFFFAOYSA-N

InChI

1S/9CO.2Fe/c9*1-2;;

SMILES string

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O

assay

98%

form

solid

reaction suitability

core: iron, reagent type: catalyst

storage temp.

2-8°C

Application

Reacts with phenylsilanes to give triply bridged diiron complexes.

pictograms

FlameSkull and crossbones

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react. 2


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Gree, R.
Synthesis, 341-341 (1989)
Kerber, R. C. et al.R. C.; Ribakove, E. C.
Organometallic News, 10, 2848-2848 (1991)
Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Crump, S. L.; Netka, J.; Rickborn, B.
The Journal of Organic Chemistry, 50, 2746-2746 (1985)
Nu Xiao et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 603-608 (2006-01-13)
[{Micro-(phthalazine-N2:N3)}Fe2(micro-CO)(CO)6](1) reacts with organolithium reagents, RLi (R = CH3, C6H5, p-CH3C6H4, p-CH3OC6H4, p-CF3C6H4, p-C6H5C6H4), followed by treatment with Me3SiCl to give the novel diiron carbonyl complexes with a saturated N-N six-membered diazane ring ligand, [{C6H4CH(R)NNCH2}Fe2(C=O)(CO)6](2, R = CH3; 3, R

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