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Merck
CN

224839

Bismuth(III) chloride

reagent grade, ≥98%

Synonym(s):

Bismuth trichloride, Trichlorobismuth

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About This Item

Empirical Formula (Hill Notation):
BiCl3
CAS Number:
7787-60-2
Molecular Weight:
315.34
NACRES:
NA.21
PubChem Substance ID:
57647987
UNSPSC Code:
12352302
EC Number:
232-123-2
MDL number:
MFCD00003461
Assay:
≥98%
Grade:
reagent grade
Form:
powder, chunks or granules

Key Documents

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Product Name

Bismuth(III) chloride, reagent grade, ≥98%

InChI key

JHXKRIRFYBPWGE-UHFFFAOYSA-K

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

SMILES string

Cl[Bi](Cl)Cl

grade

reagent grade

assay

≥98%

form

powder, chunks or granules

reaction suitability

reagent type: catalyst
core: bismuth

bp

447 °C (lit.)

mp

230-232 °C (lit.)

Quality Level

100

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Application

Bismuth(III) chloride may be used as a catalyst in the following processes:
  • Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols.
  • Preparation of thiiranes from oxiranes using ammonium thiocyanate.
  • Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates.
  • Allylation of secondary benzyl alcohols with allyltrimethylsilane.
  • [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.

General description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ7081
0000498582
0000498582
MKCZ4655
0000323952

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Daintith J
The facts on file dictionary of chemistry, 28-28 (2014)
Bismuth (III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De SK & Gibbs RA.
Tetrahedron Letters, 46(48), 8345-8350 (2005)
Bismuth (III) chloride (BiCl3)-An efficient catalyst for mild, regio-and stereoselective cleavage of epoxides with alcohols, acetic Acid and water.
Mohammadpoor-Baltork I.
Synthetic Communications, 30(13), 2365-2374 (2000)
The carbonyl-Diels-Alder reaction catalyzed by bismuth (III) chloride.
Robert H, et al.
Tetrahedron Letters, 39(10), 1161-1164 (1998)
Bismuth (III) Chloride; A Mild and Efficient Catalyst for Synthesis of Thiiranes from Oxiranes.
Mohammadpoor-Baltork I and Aliyan H.
Synthetic Communications, 28(21), 3943-3947 (1998)
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