223298
N-(Trimethylsilyl)acetamide
95%
Synonym(s):
TMS acetamide
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About This Item
Linear Formula:
CH3CONHSi(CH3)3
CAS Number:
Molecular Weight:
131.25
Beilstein:
741928
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
95%
form
solid
bp
84 °C/18 mmHg (lit.)
mp
46-49 °C (lit.)
SMILES string
CC(=O)N[Si](C)(C)C
InChI
1S/C5H13NOSi/c1-5(7)6-8(2,3)4/h1-4H3,(H,6,7)
InChI key
LWFWUJCJKPUZLV-UHFFFAOYSA-N
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General description
The efficiency of N-(Trimethylsilyl)acetamide (TMS acetamide) as allyl group scavenger and its compatibility with Fluorenylmethyloxycarbonyl chloride (Fmoc) protecting groups were studied.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
158.0 °F
Flash Point(C)
70 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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New allyl group acceptors for palladium catalyzed removal of allylic protections and transacylation of allyl carbamates.
Tetrahedron Letters, 36(32), 5741-5744 (1995)
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