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Merck
CN

221759

Ammonium cerium(IV) sulfate dihydrate

Synonym(s):

Ceric ammonium sulfate, Cerium(IV) ammonium sulfate

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About This Item

Linear Formula:
Ce(NH4)4(SO4)4 · 2H2O
CAS Number:
Molecular Weight:
632.55
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
≥94.0% (with KMnO4, redox titration)
Form:
powder
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InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

SMILES string

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI key

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

assay

≥94.0% (with KMnO4, redox titration)

form

powder

composition

Ce(IV), ≥20%

reaction suitability

reagent type: catalyst

mp

130 °C (lit.)

Quality Level

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Application

The product may be used to initiate the radical polymerization of pectin-poly(ethylene glycol) methacrylate (PEGMA) supracmolecular hydrogels. Ammonium cerium sulphate impregnated starch may be carbonized to form cerium dispersed carbon (CeDC) sorbent used for the extraction of excess fluoride in drinking water.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Cerium dispersed in carbon (CeDC) and its adsorption behavior: A first example of tailored adsorbent for fluoride removal from drinking water
Sivasankar V, et al.
Chemical Engineering Journal, 214, 45-54 (2013)
Thixotropic Supramolecular Pectin-Poly (Ethylene Glycol) Methacrylate (PEGMA) Hydrogels.
Chan SY, et al.
Polymer, 8(11), 404-404 (2016)
K H Gordon et al.
Organic letters, 3(1), 53-56 (2001-06-30)
[figure: see text] A novel benzyloxyaniline linker that uses ceric ammonium nitrate (CAN) as a cleavage reagent is described. Its application in the solid-phase synthesis of N-unsubstituted beta-lactams and secondary amides furnishes compounds in moderate to excellent yield (45-91%) and
S Kaul et al.
Amino acids, 34(2), 315-320 (2006-11-07)
An assessment of the potential of proline to scavenge free radicals was made in a couple of in vitro assay systems, namely graft co-polymerization and autooxidation of pyrogallol. Both these assays are essentially dependent upon free radical mechanisms. Graft co-polymerization
C Passirani et al.
Journal of biomaterials science. Polymer edition, 10(1), 47-62 (1999-03-26)
Nanoparticles have been obtained directly in aqueous media, from amphiphilic copolymers synthesized by radical polymerization of methyl methacrylate (MMA) initiated by Ce(IV) ions in the presence of heparin or dextran. The reaction conditions under which the copolymers spontaneously formed nanoparticles

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