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1-Fluoro-4-iodobenzene, 1-Iodo-4-fluorobenzene, 4-Fluoro-1-iodobenzene, 4-Fluorophenyl iodide, 4-Iodo-1-fluorobenzene, 4-Iodofluorobenzene, p-Fluoroiodobenzene, p-Fluorophenyl iodide, p-Iodofluorobenzene
FC6H4I
Recommended Products
Quality Level
Assay
99%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.583 (lit.)
bp
182-184 °C (lit.)
mp
−20 °C (lit.)
density
1.925 g/mL at 25 °C (lit.)
SMILES string
Fc1ccc(I)cc1
InChI
1S/C6H4FI/c7-5-1-3-6(8)4-2-5/h1-4H
InChI key
KGNQDBQYEBMPFZ-UHFFFAOYSA-N
General description
4-[18F] Fluoroiodobenzene is a versatile building block in 18F radiochemistry and is used in various transition metal-mediated C-C and C-N cross-coupling reactions. Cross-coupling reaction of 4-fluoroiodobenzene with potassium pentafluorophenyltrifluoroborate in the presence of different palladium catalysts and silver oxide in toluene has been investigated.
Application
4-Fluoroiodobenzene was used in the preparation of fluorotriphenylene derivatives.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
154.4 °F
Flash Point(C)
68 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Chemical communications (Cambridge, England), (8)(8), 894-896 (2006-02-16)
Highly substituted triphenylene derivatives were prepared in good yields via the palladium-catalyzed carbocyclization of arynes with aryl iodides.
Journal of labelled compounds & radiopharmaceuticals, 57(2), 104-109 (2014-03-29)
4-[18F]Fluoroiodobenzene ([18F]FIB) is a versatile building block in 18F radiochemistry used in various transition metal-mediated C-C and C-N cross-coupling reactions and [18F]fluoroarylation reactions. Various synthesis routes have been described for the preparation of [18F]FIB. However, to date, no automated synthesis
The effect of N-heterocyclic carbene ligands in the palladium-catalyzed cross-coupling reaction of K [C6F5BF3] with aryl iodides and aryl bromides.
Tetrahedron, 64(25), 5920-5924 (2008)
Journal of chromatography. A, 1604, 460466-460466 (2019-09-03)
Ionic liquids (ILs) are well-known in the field of separation science for their unique selectivity when used as stationary phases in gas chromatography (GC). While a significant amount of knowledge has been attained in correlating structural features of an IL
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