217344
Trichloroacetamide
99%
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
Cl3CCONH2
CAS Number:
Molecular Weight:
162.40
EC Number:
209-849-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1754028
MDL number:
InChI key
UPQQXPKAYZYUKO-UHFFFAOYSA-N
InChI
1S/C2H2Cl3NO/c3-2(4,5)1(6)7/h(H2,6,7)
SMILES string
NC(=O)C(Cl)(Cl)Cl
assay
99%
form
solid
bp
238-240 °C (lit.)
mp
139-141 °C (lit.)
General description
Trichloroacetamide is the major degradation product of trichloroacetonitrile.
Application
Trichloroacetamide was used in microarray-based transcriptomics and one-dimensional proton nuclear magnetic resonance based metabonomics to investigate the health effects of nitrogenous disinfection byproducts of trichloroacetamide in mice.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Joseph J Topczewski et al.
Journal of the American Chemical Society, 133(48), 19318-19321 (2011-11-09)
A rapid allylic fluorination method utilizing trichloroacetimidates in conjunction with an iridium catalyst has been developed. The reaction is conducted at room temperature under ambient air and relies on Et(3)N·3HF reagent to provide branched allylic fluorides with complete regioselectivity. This
Jeffrey S Arnold et al.
Chemical communications (Cambridge, England), 48(94), 11531-11533 (2012-10-24)
We report the chiral diene ligated rhodium-catalyzed dynamic kinetic asymmetric transformation (DYKAT) of racemic secondary allylic trichloroacetimidates with a variety of N-methyl anilines, providing allylic N-methyl arylamines in high yields, regioselectivity, and enantiomeric excess. The rhodium-catalyzed DYKAT method addresses limitations
Tatsuya Komori et al.
Carbohydrate research, 344(12), 1453-1463 (2009-06-30)
A first systematic synthesis of the glycan parts of the a-series gangliosides (GT1a, GD1a, and GM1) utilizing the newly developed N-Troc-protected GM3 and galactosaminyl building blocks is described. The key processes, including the assembly of the GM2 sequence and its
Yan Zhang et al.
Environmental science & technology, 47(6), 2918-2924 (2013-02-15)
Microarray-based transcriptomics and one-dimensional proton nuclear magnetic resonance ((1)H NMR) based metabonomics approaches were employed to investigate the health effects of nitrogenous disinfection byproducts (N-DBPs) of trichloroacetamide (TCAcAm) on mice. Mice were exposed to TCAcAm at concentrations of 50, 500
Nihan Celebi-Olçüm et al.
The Journal of organic chemistry, 74(18), 6944-6952 (2009-08-20)
Density functional theory calculations were used to investigate the [3,3]- and [1,3]-shifts of O-allylic trichloroacetimidates in the presence of cinchona alkaloids. Thermal [1,3]- and [3,3]-rearrangements proceed through concerted pseudopericyclic transition states to give the corresponding rearranged products. [1,3]-Rearrangement is catalyzed
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service