212970
2-(Bromomethyl)acrylic acid
98%
Synonym(s):
α-(Bromomethyl)acrylic acid, 2-(Bromomethyl)-2-propenoic acid, Bromomethylacrylic acid
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About This Item
Linear Formula:
CH2=C(CH2Br)COOH
CAS Number:
Molecular Weight:
164.99
Beilstein:
2426204
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
Assay
98%
form
solid
mp
70-73 °C (lit.)
storage temp.
2-8°C
SMILES string
OC(=O)C(=C)CBr
InChI
1S/C4H5BrO2/c1-3(2-5)4(6)7/h1-2H2,(H,6,7)
InChI key
NOOYFQLPKUQDNE-UHFFFAOYSA-N
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Application
Reacts with aldehydes and ketones to form α-methylene-butyrolactones. Used in the synthesis of methotrexate analogues.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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A Abraham et al.
Journal of medicinal chemistry, 34(1), 222-227 (1991-01-01)
Five analogues of methotrextate (MTX), 10-deazaaminopterin (10-DAM), and 10-ethyl-10-deazaaminopterin (10-EDAM) in which the glutamate moiety was replaced by either a gamma-methyleneglutamate or beta-hydroxyglutamate were synthesized and evaluated for their antifolate activity. These analogous are 4-amino-4-deoxy-N10-methylpteroyl-beta-hydroxyglutamic acid (1), 4-amino-4-deoxy-10-deazapteroyl-beta-hydroxyglutamic acid (2)
Synthesis, 530-530 (1990)
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