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About This Item
Empirical Formula (Hill Notation):
Zn
CAS Number:
Molecular Weight:
65.39
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
vapor pressure
1 mmHg ( 487 °C)
Quality Level
Assay
≥98%
form
dust
reaction suitability
core: zinc
reagent type: catalyst
resistivity
5.8 μΩ-cm, 20°C
particle size
<10 μm
bp
907 °C (lit.)
mp
420 °C (lit.)
density
7.133 g/mL at 25 °C (lit.)
SMILES string
[Zn]
InChI
1S/Zn
InChI key
HCHKCACWOHOZIP-UHFFFAOYSA-N
Related Categories
General description
Zinc is an inexpensive, readily available versatile reagent in organic reactions and is commonly used as a reducing agent in organic synthesis. Zinc dust is used to reduce carbonyls, carbon-halide bonds, carbon-oxygen bonds, alkynes, and heteroatom bonds such as N-N and N-O bonds. It is also used to prepare various organozinc reagents. Additionally, Zinc has been used in several well-known named reactions, like the Reformatsky reaction, the Knorr pyrrole synthesis, the Serini reaction, and the Simmons-Smith cyclopropanation.
Application
Reducing agent; used for preparation of organozinc reagents, Reformatsky reagents, and the Simmons-Smith reagent (cyclopropanation).
Zinc is also used as a:
Zinc is also used as a:
- Reductant in the hydrothermal CO2 reduction to formic acid in batch reactors.
- Catalyst in the synthesis of propargylamines by one pot, three component coupling of aldehydes, amines and alkynes in acetonitrile.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
监管及禁止进口产品
Certificates of Analysis (COA)
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Activated zinc dust
Smith CR
Synlett, 2009(09), 1522-1523 (2009)
Nicholas A Isley et al.
Green chemistry : an international journal and green chemistry resource : GC, 2015, 307-307 (2014-12-23)
Alkyl bromides and chlorides can be reduced to the corresponding hydrocarbons utilizing zinc in the presence of an amine additive. The process takes place in water at ambient temperatures, enabled by a commercially available designer surfactant. The reaction medium can
Efficient one-pot synthesis of propargylamines using zinc dust
Kantam ML, et al.
Tetrahedron Letters, 48(41), 7332-7334 (2007)
Knochel, P.
Chemical Reviews, 93, 217-217 (1993)
Sara Eyal et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 50(5), 798-806 (2009-05-01)
Studies in rodents indicate that the disruption of P-glycoprotein (P-gp) function increases drug distribution into the developing fetus and organs such as the brain. To simultaneously and serially evaluate the effect of P-gp activity and inhibition on the tissue distribution
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