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Merck
CN

208248

Aluminum acetylacetonate

98%

Synonym(s):

Al(acac)3, Aluminum 2,4-pentanedionate

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About This Item

Linear Formula:
Al(C5H7O2)3
CAS Number:
Molecular Weight:
324.31
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-741-6
Beilstein/REAXYS Number:
4157942
MDL number:
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InChI key

KILURZWTCGSYRE-LNTINUHCSA-K

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

assay

98%

form

solid

reaction suitability

core: aluminum

bp

315 °C (lit.)

mp

190-193 °C (lit.)

Quality Level

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General description

Alumunium acetylacetonate is insoluble in water but soluble in organic solvents. It reacts with alkalis, acids, water at elevated temperatures. It can be prepared by reacting AlCl3 and acetylacetonate.

Application

Alumunium acetylacetonate may be used:
  • to prepare transparent superhydrophobic boehmite and silica films by sublimation,
  • to deposit alumunium oxide films by chemical vapor deposition,
  • as a catalyst.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

244.4 °F

flash_point_c

118 °C

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate.
Nakajima A, et al.
Advanced Mat., 11(16), 1365-1368 (1999)
Aluminum oxide thin films prepared by chemical vapor deposition from aluminum acetylacetonate
Maruyama T, et al.
Applied Physics Letters, 60(3), 322-323 (1992)
P Zatta et al.
Molecular and chemical neuropathology, 16(1-2), 11-22 (1992-02-01)
Murine neuroblastoma cells behave differently in the presence of Al(acac)3 [acac = 2,4-pentanedionate; acetylacetonate] or Al(malt)3 [malt = 3-hydroxy, 2-methyl, 4-pyronate; maltolate] with respect to Al(lac)3 [lac = 2-hydroxypropionate; lactate]. Thus, a remarkable cytotoxic effect was observed in the first
Does aluminum lactate cause spinal cord infarction in rabbits?
S Levine
Environmental health perspectives, 96, 245-245 (1991-12-01)
P Zatta et al.
Neuroreport, 4(9), 1119-1122 (1993-09-01)
The present paper reports data concerning aluminum accumulation and compartmentation in the central nervous system from rats exposed by inhalation to aluminum acetylacetonate [Al(acac)3] for two weeks. The complex Al(aca)3 was chosen for being neutral, hydrolytically stable and lipophilic. After

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