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Merck
CN

206245

Iridium(III) chloride hydrate

reagent grade, solid

Synonym(s):

IrCl3, Iridium trichloride hydrate

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About This Item

Linear Formula:
IrCl3 · xH2O
CAS Number:
14996-61-3
Molecular Weight:
298.58 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
24852388
UNSPSC Code:
12161600
EC Number:
233-044-6
MDL number:
MFCD00149749

Key Documents

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Product Name

Iridium(III) chloride hydrate, reagent grade

InChI key

MJRFDVWKTFJAPF-UHFFFAOYSA-K

InChI

1S/3ClH.Ir.H2O/h3*1H;;1H2/q;;;+3;/p-3

SMILES string

[H]O[H].Cl[Ir](Cl)Cl

grade

reagent grade

form

solid

reaction suitability

core: iridium
reagent type: catalyst

density

5.3 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

100

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Application

Iridium(III) chloride hydrate can be used as a precursor in the preparation of:
  • Iridium-incorporated cobalt nanofibers.
  • Carbon-supported iridium catalyst for the hydrodeoxygenation of hydroxymethylfurfural.

General description

Iridium(III) chloride hydrate is an inorganic compound used as a catalyst as well as a reagent in organic synthesis. It is used as the source of iridium in the preparation of iridium nanocatalysts.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ7549
MKCZ1520
MKCX7728
MKCX2033
MKCW0748

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?Naked? iridium (IV) oxide nanoparticles as expedient and robust catalysts for hydrogenation of nitrogen heterocycles: remarkable vicinal substitution effect and recyclability
Ji YG, et al.
Advanced Synthesis & Catalysis, 359, 933-940 (2017)
Comparison of HMF hydrodeoxygenation over different metal catalysts in a continuous flow reactor
Applied Catalysis A: General, 508, 86-93 (2015)
Maximilian Moser et al.
Angewandte Chemie (International ed. in English), 53(33), 8628-8633 (2014-06-04)
Rutile TiO2 is a heavily investigated oxide with, to date, scarce applications in industrial catalysis. The inactivity of this material in oxidations has been related to its inability to dissociate molecular oxygen. Herein we show how rutile catalyzes the oxidation

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