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Sigma-Aldrich

Tetraamminepalladium(II) chloride monohydrate

98%

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Synonym(s):
Tetraamminepalladium(2+) dichloride monohydrate
Linear Formula:
Pd(NH3)4Cl2·H2O
CAS Number:
13933-31-8
Molecular Weight:
263.46
EC Number:
237-489-7
MDL number:
MFCD00151033
UNSPSC Code:
12161600
PubChem Substance ID:
24852351
NACRES:
NA.22

Quality Level

100

Assay

98%

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

120 °C (dec.) (lit.)

density

1.91 g/mL at 25 °C (lit.)

SMILES string

N.N.N.N.O.Cl[Pd]Cl

InChI

1S/2ClH.4H3N.H2O.Pd/h2*1H;4*1H3;1H2;/q;;;;;;;+2/p-2

InChI key

WVCXSPJPERKPJS-UHFFFAOYSA-L

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General description

Tetraamminepalladium (II) chloride monohydrate is a coordination complex that is used as a catalyst and as a precursor to synthesize other palladium compounds.

Application

Tetraamminepalladium(II) chloride monohydrate can be used as a precursor in the synthesis of Pd (II) complex that is immobilized on hydrophilic graphite oxide for its use as a catalyst in the Heck coupling reaction.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Immobilization of a Pd (II) complex on hydrophilic graphite oxide and its catalytic investigation in the Heck coupling reaction
Mastalir A, et al.
Applied Organometallic Chemistry, 34(4), e5565-e5565 (2020)
The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles
Gotoh K, et al.
Carbon, 47(8), 2120-2214 (2009)
Surface engineering of a supported PdAg catalyst for hydrogenation of CO2 to formic acid: elucidating the active Pd atoms in alloy nanoparticles
Mori K, et al.
Journal of the American Chemical Society, 140(28), 8902-8909 (2018)

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