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200913

Sigma-Aldrich

Potassium hexafluorophosphate

≥99%

Synonym(s):

Monopotassium hexafluorophosphate

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About This Item

Linear Formula:
KPF6
CAS Number:
17084-13-8
Molecular Weight:
184.06
EC Number:
241-143-0
MDL number:
MFCD00011412
UNSPSC Code:
12352302
PubChem Substance ID:
24851982
NACRES:
NA.23

Quality Level

200

Assay

≥99%

form

solid

technique(s)

ion chromatography: suitable

mp

575 °C (lit.)

density

2.75 g/mL at 25 °C (lit.)

SMILES string

[K+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.K/c1-7(2,3,4,5)6;/q-1;+1

InChI key

YZDGRYDIGCWVND-UHFFFAOYSA-N

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Application

Potassium hexafluorophosphate can be used as an electrolyte additive to improve the:
  • Electrochemical performance of an anode-free lithium metal battery.
  • Cycling stability and Li Coulombic efficiency of lithium-sulfur(Li–S) batteries.
It can also be used as interface modification material to passivate interface defects in perovskite solar cells.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Jingru Li et al.
ACS applied materials & interfaces, 12(50), 56017-56026 (2020-12-04)
Uncontrollable dendrite growth and low Coulombic efficiency are the two main obstacles that hinder the application of rechargeable Li metal batteries. Here, an optimized amount of potassium hexafluorophosphate (KPF6, 0.01 M) has been added into the 2 M LiTFSI/ether-based electrolyte
Ruhamah Yunis et al.
Physical chemistry chemical physics : PCCP, 21(23), 12288-12300 (2019-05-30)
The synthesis and characterisation of new solid-state electrolytes is a key step in advancing the development of safer and more reliable electrochemical energy storage technologies. Organic ionic plastic crystals (OIPCs) are an increasingly promising class of material for application in
Cong-Xiao Cao et al.
Scientific reports, 7(1), 3101-3101 (2017-06-10)
The unusually broad physical and chemical property window of ionic liquids allows for a wide range of applications, which gives rise to the recent spring-up of ionic liquid-based functional materials. Via solvothermal copolymerization of a monomeric ionic liquid and divinylbenzene
Yuexi Yang et al.
Molecules (Basel, Switzerland), 25(9) (2020-05-02)
The use of baker's yeast to reduce ethyl 2-oxo-4-phenylbutyrate (EOPB) in conventional biphasic systems is hindered by low productivities due to mass transfer resistance between the biocatalyst and the substrate partitioned into two different phases. To overcome the limitation, a
Barbara Pawłowska et al.
Journal of agricultural and food chemistry, 67(11), 3086-3095 (2019-02-26)
In this study, new chiral ionic liquids (CILs) were obtained from the natural-origin material (1 R,2 S,5 R)-(-)-menthol. The physicochemical characteristics of the studied imidazolium salts were investigated. The obtained 3-ethyl-1-[(1 R,2 S,5 R)-(-)-menthoxy-methyl]imidazolium salts are nonvolatile, nonflammable, and stable
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