200050
Chromium(III) chloride
purified by sublimation, 99%
Synonym(s):
Chromic chloride, Chromium trichloride
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About This Item
Linear Formula:
CrCl3
CAS Number:
Molecular Weight:
158.36
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
99%
form:
flakes
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Quality Level
Assay
99%
form
flakes
purified by
sublimation
reaction suitability
reagent type: catalyst
core: chromium
impurities
<0.2% water
density
2.87 g/mL at 25 °C (lit.)
SMILES string
Cl[Cr](Cl)Cl
InChI
1S/3ClH.Cr/h3*1H;/q;;;+3/p-3
InChI key
QSWDMMVNRMROPK-UHFFFAOYSA-K
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Application
Chromium(III) chloride can be used in the formation of a catalytic system for the conversion of glucose into 5-hydroxymethylfurfural (HMF). It can also be used in the preparation of ionic liquid mixtures using choline chloride and water with improved ion mobility and conductivity.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.2
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Physicochemical properties of ionic liquid mixtures containing choline chloride, chromium (III) chloride and water: effects of temperature and water content
Protsenko VS, et al.
Ionics, 23(3), 637-643 (2017)
Efficient conversion of glucose into 5-hydroxymethylfurfural by chromium (III) chloride in inexpensive ionic liquid
Hu L, et al.
Industrial & Engineering Chemistry Research, 51(3), 1099-1104 (2012)
Narsi R Bishnoi et al.
Journal of hazardous materials, 145(1-2), 142-147 (2006-12-07)
In the present investigation, a fresh water green algae spirogyra spp. was used as an inexpensive and efficient biosorbent for Cr(III) removal from aqueous solution. The algal biomass was treated with 0.1M NaOH, 0.2M CaCl(2) and 5% HCHO. The biosorption
Malene Barré Hansen et al.
Contact dermatitis, 54(3), 140-144 (2006-03-10)
Chromium allergy has become synonymous with Cr(VI) allergy. However, real exposure to chromium from leather products may include both Cr(III) and Cr(VI). In this study, we investigate the reactivity to both Cr(VI) and Cr(III) in consecutive patients to analyse the
Yu-Fei Song et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1864-1871 (2008-03-29)
The coordination chemistry of CrCl3 with three pentadentate ligands having the [1,4,7]-triazacyclononane-1,4-diacetato motif have been investigated. The new resulting six-coordinate Cr(iii)-chloro species react cleanly with sodium azide to form the corresponding azido species, which undergo photolysis under irradiation at 419
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