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About This Item
Empirical Formula (Hill Notation):
C4H6O
CAS Number:
Molecular Weight:
70.09
Beilstein:
103168
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor pressure
14.46 psi ( 55 °C)
3.67 psi ( 20 °C)
Quality Level
Assay
99%
form
liquid
refractive index
n20/D 1.423 (lit.)
bp
54-55 °C (lit.)
density
0.927 g/mL at 25 °C (lit.)
functional group
ether
storage temp.
2-8°C
SMILES string
C1CC=CO1
InChI
1S/C4H6O/c1-2-4-5-3-1/h1,3H,2,4H2
InChI key
JKTCBAGSMQIFNL-UHFFFAOYSA-N
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General description
The enantioselective Heck arylation of 2,3-dihydrofuran with aryl iodides was studied.
Application
2,3-Dihydrofuran is a versatile reagent used in lanthanide-catalyzed Diels-Alder reactions with 2-pyrones and in Rh(II)-stabilized cycloadditions with vinylcarbenoids.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-11.2 °F - closed cup
Flash Point(C)
-24 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Claudia G Cobo-Angel et al.
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Synlett, 431-431 (1994)
Tetrahedron, 50, 4557-4557 (1994)
The Journal of Organic Chemistry, 59, 4535-4535 (1994)
Wen-Qiong Wu et al.
Journal of the American Chemical Society, 130(30), 9717-9725 (2008-07-02)
A series of benzylic substituted P, N-ligands 1 and 2 have been synthesized. The Pd-complexes of these ligands show high catalytic activity and enantioselectivity in catalyzing the asymmetric Heck reaction. A dramatic switch in enantioselectivity is realized using ligands with
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