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196274

Thiomorpholine

Name: Thiomorpholine
Brand: ALDRICH

98%

Synonym(s):

Tetrahydro-2H-1,4-thiazine, Thiamorpholine

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About This Item

Empirical Formula (Hill Notation):

C₄H₉NS

CAS Number:

123-90-0

Molecular Weight:

103.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24851748

EC Number:

204-660-2

Beilstein/REAXYS Number:

102550

MDL number:

MFCD00005974

Assay:

98%

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Properties

Quality Level

100

assay

98%

refractive index

n20/D 1.538 (lit.)

bp

169 °C (lit.)

solubility

organic solvents: miscible(lit.), water: miscible(lit.)

density

1.026 g/mL at 25 °C (lit.)

functional group

thioether

SMILES string

C1CSCCN1

InChI

1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2

InChI key

BRNULMACUQOKMR-UHFFFAOYSA-N

Description

General description

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.

Application

Thiomorpholine has been used in the preparation of:

N-Boc-α-alkyl-β-(sec-amino)alanines
thiomorpholine-N-borane

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 + P310 - P501

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite.

Amezcua CA, et al.

Inorgorganica Chimica Acta, 290(1), 80-85 (1999)

Complexation, thermal and catalytic studies of N-substituted piperazine, morpholine and thiomorpholine with some metal ions.

Mesut Kacan et al.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 572-577 (2013-10-05)

Several Cu(II), Pt(II) and Ni(II) complexes of N-substituted, piperazine (NN donor), morpholine (NO donor) and thiomorpholine (NS donor) derivatives were synthesized and their thermal behavior and catalytic activity in epoxidation reaction of cis-diphenylethylene were studied using oxygen sources NaOCl. The

Thiomorpholine and morpholine oxidation by a cytochrome P450 in Mycobacterium aurum MO1. Evidence of the intermediates by in situ 1H NMR.

B Combourieu et al.

Biodegradation, 9(6), 433-442 (1999-05-21)

Spectrophotometric assays of Mycobacterium aurum MO1 cells extracts gave evidence of a soluble cytochrome P450, involved in the degradative pathway of morpholine, a waste product from the chemical industry. In order to get further information, the kinetics of the biodegradation

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Global Trade Item Number

SKU	GTIN
196274-25G	04061838118493
196274-5G	04061838761996