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195537

tert-Butyl(chloro)diphenylsilane

Name: <I>tert</I>-Butyl(chloro)diphenylsilane
Brand: ALDRICH

98%

Synonym(s):

tert-Butyldiphenylchlorosilane, TBDPSCl

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About This Item

Linear Formula:

(CH₃)₃CSi(C₆H₅)₂Cl

CAS Number:

58479-61-1

Molecular Weight:

274.86

Beilstein:

644023

EC Number:

261-282-0

MDL number:

MFCD00000497

UNSPSC Code:

12352002

PubChem Substance ID:

24851697

NACRES:

NA.22

Quality Level

200

Assay

98%

form

liquid

refractive index

n20/D 1.568 (lit.)

bp

90 °C/0.01 mmHg (lit.)

density

1.057 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)[Si](Cl)(c1ccccc1)c2ccccc2

InChI

1S/C16H19ClSi/c1-16(2,3)18(17,14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3

InChI key

MHYGQXWCZAYSLJ-UHFFFAOYSA-N

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Related Categories

Protection/Deprotection Reagents

Silanes

Application

Silylating reagent used in the protection of alcohols and the preparation of silyl ethers.

Pictograms

GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H335

Precautionary Statements

P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

>230.0 °F

Flash Point(C)

> 110 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Polish Journal of Chemistry, 67, 685-685 (1993)

Tetrahedron Letters, 34, 3821-3821 (1993)

Phosphorus-containing inhibitors of HMG-CoA reductase. 2. Synthesis and biological activities of a series of substituted pyridines containing a hydroxyphosphinyl moiety.

J A Robl et al.

Journal of medicinal chemistry, 34(9), 2804-2815 (1991-09-11)

A series of 2,3,4,(5),6-substituted pyridines containing a hydroxyphosphinyl functionally have been prepared and were evaluated for their ability to inhibit the enzyme HMG-CoA reductase. Systematic substitution of both R1-R4 and X-Y led to compounds of type 3-6 with in vitro

Regioselective copolymerization of acryl sucrose monomers.

Maria Teresa Barros et al.

The Journal of organic chemistry, 69(22), 7772-7775 (2004-10-23)

1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.

Polyphosphates and pyrophosphates of hexopyranoses as allosteric effectors of human hemoglobin: synthesis, molecular recognition, and effect on oxygen release.

Konstantina C Fylaktakidou et al.

ChemMedChem, 6(1), 153-168 (2010-11-26)

Polyphosphorylated and perphosphorylated hexopyranose monosaccharides and disaccharides were synthesized from parent or partially protected carbohydrates as potential allosteric effectors of hemoglobin. A study toward the construction of seven- and eight-membered cyclic pyrophosphates was also performed on the sugars which had

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