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Merck
CN

192759

Ethylaluminum dichloride solution

25 wt. % in toluene

Synonym(s):

Dichloroethylaluminum, Dichloromonoethylaluminum, Ethylaluminium dichloride, Ethylaluminum dichloride (6CI), Ethyldichloroaluminium, Ethyldichloroaluminum

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About This Item

Linear Formula:
CH3CH2AlCl2
CAS Number:
563-43-9
Molecular Weight:
126.95
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24851563
MDL number:
MFCD00000457
Beilstein/REAXYS Number:
4123357

Key Documents

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Product Name

Ethylaluminum dichloride solution, 25 wt. % in toluene

InChI

1S/C2H5.Al.2ClH/c1-2;;;/h1H2,2H3;;2*1H/q;+2;;/p-2

SMILES string

CC[Al](Cl)Cl

InChI key

UAIZDWNSWGTKFZ-UHFFFAOYSA-L

vapor pressure

5 mmHg ( 60 °C)

form

liquid

concentration

25 wt. % in toluene

density

0.927 g/mL at 25 °C

Quality Level

100

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Related Categories

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1

target_organs

Central nervous system

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

39.2 °F - closed cup - Solvent

flash_point_c

4 °C - closed cup - Solvent

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBS0203
SHBP8335
SHBK6673
SHBF6791V
00797TJ

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Barry B Snider et al.
The Journal of organic chemistry, 68(16), 6451-6454 (2003-08-05)
EtAlCl(2)-induced cyclization of chiral gamma,delta-unsaturated ketones 11c and 17b takes place mainly from the expected face. The selectivity is modest for 11c (60:40) in which the large substituent is a primary alkyl group and the medium substituent is a methyl

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