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Merck
CN

192716

Triisobutylaluminum solution

25 wt. % in toluene

Synonym(s):

TIBA solution

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About This Item

Linear Formula:
[(CH3)2CHCH2]3Al
CAS Number:
100-99-2
Molecular Weight:
198.32
PubChem Substance ID:
24851560
UNSPSC Code:
12352103
Beilstein/REAXYS Number:
3587328
MDL number:
MFCD00008929

Key Documents

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SMILES string

CC(C)C[Al](CC(C)C)CC(C)C

InChI

1S/3C4H9.Al/c3*1-4(2)3;/h3*4H,1H2,2-3H3;

InChI key

MCULRUJILOGHCJ-UHFFFAOYSA-N

form

liquid

concentration

25 wt. % in toluene

density

0.848 g/mL at 25 °C

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signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react. 1

target_organs

Central nervous system

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

-0.4 °F - closed cup

flash_point_c

-18 °C - closed cup

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
14110BF
04020BN
00820KU
00508KR
00325JY

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Nandita M Weliange et al.
Dalton transactions (Cambridge, England : 2003), 44(34), 15286-15296 (2015-06-05)
The insertion, elimination and isomerisation of octenes with di-n-octylaluminium hydride [HAl(Oct)2], tri-n-octylaluminium [Al(Oct)3] and sec-octylaluminium species have been studied as individual steps in a putative aluminium based contrathermodynamic olefin isomerisation process. While elimination of 1-octene from [Al(Oct)3] is energetically unfavourable
Yunhong Zhang et al.
Carbohydrate polymers, 113, 446-454 (2014-09-27)
Alginate oligosaccharides (AOS), which are marine oligosaccharides, are involved in regulating plant root growth, but the promotion mechanism for AOS remains unclear. Here, AOS (10-80 mg/L) induced the expression of auxin-related gene (OsYUCCA1, OsYUCCA5, OsIAA11 and OsPIN1) in rice (Oryza
Inmaculada Suárez et al.
Journal of chromatography. A, 1407, 193-202 (2015-07-15)
Average molecular weights and polydispersity indexes are some of the most important parameters considered in the polymer characterization. Usually, gel permeation chromatography (GPC) and multi angle light scattering (MALS) are used for this determination, but GPC values are overestimated due

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