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189006

(+)-3-(Trifluoroacetyl)camphor

Name: (+)-3-(Trifluoroacetyl)camphor
Brand: ALDRICH

98%

Synonym(s):

3-(Trifluoroacetyl)-D-camphor

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About This Item

Empirical Formula (Hill Notation):

C₁₂H₁₅F₃O₂

CAS Number:

51800-98-7

Molecular Weight:

248.24

Beilstein:

6779716

EC Number:

257-429-3

MDL number:

MFCD00003746

UNSPSC Code:

12352115

PubChem Substance ID:

24851361

NACRES:

NA.22

Assay

98%

form

liquid

optical activity

[α]19/D +148°, c = 2.3 in methylene chloride

refractive index

n20/D 1.451 (lit.)

bp

100-101 °C/16 mmHg (lit.)

density

1.172 g/mL at 25 °C (lit.)

SMILES string

CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)F

InChI

1S/C12H15F3O2/c1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1

InChI key

ISLOIHOAZDSEAJ-XGLFCGLISA-N

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Chiral Catalysts & Ligands

Application

(+)-3-(Trifluoroacetyl)camphor reacts with suitable chiral ketone precursors to generate chiral dioxiranes in situ, which can catalyse the direct asymmetric epoxidation of unfunctionalized olefins.

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Enantioselective epoxidation of unfunctionalized alkenes using dioxiranes generated in situ.

Curci R, et al.

Tetrahedron Letters, 36(32), 5831-5834 (1995)

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