All Photos(2)
Synonym(s):
(4-Bromophenyl)methanol, (p-Bromophenyl)methanol, 1-(p-Bromophenyl)methanol, 1-Bromo-4-(hydroxymethyl)benzene, 4-Hydroxymethyl-1-bromobenzene, p-Bromobenzyl alcohol
Linear Formula:
BrC6H4CH2OH
CAS Number:
Molecular Weight:
187.03
Beilstein:
1931620
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
form
solid
mp
75-77 °C (lit.)
solubility
dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow
SMILES string
OCc1ccc(Br)cc1
InChI
1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
InChI key
VEDDBHYQWFOITD-UHFFFAOYSA-N
Gene Information
human ... ALOX12(239) , ALOX15(246)
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General description
4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Application
4-Bromobenzyl alcohol was used in the synthesis of:
- hydroxyl end functionalized, substituted polyfluorene
- amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Qianyan Li et al.
International journal of nanomedicine, 15, 4825-4845 (2020-08-06)
Nanosized drug delivery systems (NDDSs) have shown excellent prospects in tumor therapy. However, insufficient penetration of NDDSs has significantly impeded their development due to physiological instability and low passive penetration efficiency. Herein, we prepared a core cross-linked pullulan-modified nanosized system
Synthesis of an Amphiphilic p-Conjugated Triblock Copolymer of Poly (9, 9-didodecylfluorene-2, 7-diyl) and Poly (hydroxyl ethyl methacrylate).
Kim HJ, et al.
Macromolecular Research, 13(6), 529-532 (2005)
C Ho et al.
Progress in clinical and biological research, 240, 59-66 (1987-01-01)
Two new techniques of nuclear magnetic resonance spectroscopy are proposed to identify and characterize the binding sites of antisickling compounds to Hb S: measurements of the longitudinal relaxation rates (T1(-1)) of the C2 protons of individual surface histidyl residues of
I M Russu et al.
Biochemistry, 25(4), 808-815 (1986-02-25)
High-resolution proton nuclear magnetic resonance spectroscopy and relaxation techniques have been used to investigate the interactions of sickle cell hemoglobin (Hb S) and human normal adult hemoglobin (Hb A) with p-bromobenzyl alcohol, L-phenylalanine, L-tryptophan, and L-valine. With the exception of
Shaodong Zhai et al.
Biomaterials, 121, 41-54 (2017-01-10)
Undesired physiological instability of nanocarriers and premature drug leakage during blood circulation result in compromised therapeutic efficacy and severe side effects, which have significantly impeded the development of nanomedicine. Facile crosslinking of drug-loaded nanocarriers while keeping the potency of site-specific
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