All Photos(1)
Linear Formula:
FC6H4COCH3
CAS Number:
Molecular Weight:
138.14
Beilstein:
2041344
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
form
liquid
refractive index
n20/D 1.507 (lit.)
bp
187-189 °C (lit.)
density
1.137 g/mL at 20 °C (lit.)
SMILES string
CC(=O)c1ccccc1F
InChI
1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI key
QMATYTFXDIWACW-UHFFFAOYSA-N
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General description
The enantioselective reduction of 2′-fluoroacetophenone has been investigated.
Application
2′-Fluoroacetophenone was used as starting reagent in the synthesis of ascididemin.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
WGK
WGK 3
Flash Point(F)
143.6 °F
Flash Point(C)
62 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Ida Nymann Petersen et al.
Chemical communications (Cambridge, England), 48(72), 9092-9094 (2012-08-07)
A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended
The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure.
Garrett CE, et al.
Tetrahedron Asymmetry, 13(13), 1347-1349 (2002)
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