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Sigma-Aldrich

Tetrathiafulvalene

97%

Synonym(s):

Δ2,2′-Bi-1,3-dithiole, TTF

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About This Item

Empirical Formula (Hill Notation):
C6H4S4
CAS Number:
Molecular Weight:
204.36
Beilstein:
1617956
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

97%

form

solid

mp

116-119 °C (lit.)

SMILES string

S1C=CS\C1=C2/SC=CS2

InChI

1S/C6H4S4/c1-2-8-5(7-1)6-9-3-4-10-6/h1-4H

InChI key

FHCPAXDKURNIOZ-UHFFFAOYSA-N

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General description

Tetrathiafulvalene (TTF) is an electron-donor which consists of oligomers, dendrimers and polymers which can be used in the formation of redox macromolecules.

Application

TTF may be linked with lithium chloride (LiCl) to form a precipitated layer on the lithium oxide (Li2O2) for the fabrication of high performance Li-O2 batteries. Bio-sourced carbon nanodots can be surface modified by TTF which can be potentially used for electrochemical applications.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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S Popat et al.
Annals of oncology : official journal of the European Society for Medical Oncology, 31(12), 1734-1745 (2020-09-26)
Malignant pleural mesothelioma (MPM) is an aggressive malignancy characterised by limited treatment options and a poor prognosis. At relapse after platinum-based chemotherapy, single-agent chemotherapy is commonly used and single-arm trials of immune-checkpoint inhibitors have demonstrated encouraging activity. PROMISE-meso is an
José L. Segura et al.
Angewandte Chemie (International ed. in English), 40(8), 1372-1409 (2001-04-24)
Tetrathiafulvalene (TTF) and its derivatives were originally prepared as strong electron-donor molecules for the development of electrically conducting materials. This Review emphasizes how TTF and its derivatives offer new and in some cases little-exploited possibilities at the molecular to the
T R Converso et al.
Vaccine, 35(1), 149-155 (2016-11-26)
Streptococcus pneumoniae (pneumococcus) is a human pathogen that can cause otitis media, pneumonia and, in severe cases, meningitis and bacteremia. The pneumococcus expresses PotD, a protein belonging to the polyamines transporter complex called PotABCD. PotD is a membrane-associated protein that
Modified Tetrathiafulvalene as an Organic Conductor for Improving Performances of Li- O2 Batteries.
Zhang J, et al.
Angewandte Chemie (International Edition in English), 56(29), 8505-8509 (2017)
Hong-Jing Zhu et al.
Nature communications, 11(1), 497-497 (2020-01-26)
Efficient conversion of carbon dioxide (CO2) into value-added products is essential for clean energy research. Design of stable, selective, and powerful electrocatalysts for CO2 reduction reaction (CO2RR) is highly desirable yet largely unmet. In this work, a series of metalloporphyrin-tetrathiafulvalene based

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