181498
Polyisobutylene
average Mw ~4,200,000, average Mn ~3,100,000 by GPC/MALLS, average Mv ~4,700,000
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form
slab/chunk
mol wt
average Mn ~3,100,000 by GPC/MALLS
average Mv ~4,700,000
average Mw ~4,200,000
contains
500 ppm BHT as stabilizer
refractive index
n20/D 1.51
density
0.92 g/mL at 25 °C (lit.)
SMILES string
CC(C)=C
InChI
1S/C4H8/c1-4(2)3/h1H2,2-3H3
InChI key
VQTUBCCKSQIDNK-UHFFFAOYSA-N
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General description
Polyisobutylene (PIB) is an elastomer and plasticizer.It exhibits good gas permeability, thermal, oxidative and chemical stability. Films of PIB can be synthesized by RF sputtering, whereas branched PIB can be synthesized from 4-(1-hydroxy-1-methylethyl)styrene -co-styrene (HMESt-co-St) as inimer.
Application
PIB may be used to prepare polymers blends with isotactic polypropylene (iPP).
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Morphology, crystallization and melting behaviour of films of isotactic polypropylene blended with ethylene-propylene copolymers and polyisobutylene,
Polymer, 23(2), 229-237 (1982)
Dynamic rheological properties of polyisobutylene
Journal of Applied Polymer Science, 20, 193-206 (1976)
Langmuir : the ACS journal of surfaces and colloids, 26(10), 7574-7581 (2010-01-29)
Organic-inorganic hybrid materials attract particular interest because of their excellent mechanical properties. Here, we report the synthesis of hybrid cryogels consisting of interpenetrated polyisobutylene and silica networks. The gels were prepared by cross-linking of butyl rubber in cyclohexane containing silica
Journal of the American Chemical Society, 134(36), 14714-14717 (2012-08-29)
The studies described here show that a relatively low molecular weight, narrow polydispersity polyethylene (PE) wax (Polywax) can serve as a nontoxic and nonvolatile alternative to alkane solvents in monophasic catalytic organic reactions where catalysts and products are separated under
Biomaterials, 31(9), 2477-2488 (2009-12-26)
This paper presents the synthesis and characterization of a polyisobutylene (PIB)-based nanostructured carbon-reinforced thermoplastic elastomer. This thermoplastic elastomer is based on a self-assembling block copolymer having a branched PIB core carrying -OH functional groups at each branch point, flanked by
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