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Merck
CN

181374

Polybutadiene, cis

average Mw 200,000-300,000

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About This Item

Linear Formula:
(CH2CH=CHCH2)n
CAS Number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
MDL number:
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Product Name

Polybutadiene, cis, average Mw 200,000-300,000

SMILES string

C\C=C\C

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

description

98% cis

form

slab/chunk

mol wt

average Mw 200,000-300,000

viscosity

40, Mooney(lit.)

transition temp

Tg −102 °C

density

0.9 g/mL at 25 °C (lit.)

Quality Level

Application

PB-cis can be polymerized with styrene for the formation of high impact polystyrene (HIPS). It may also be used as a toughening agent for acrylonitrile butadiene rubber (ABS) based resins.

General description

Polybutadiene, cis (PB-cis) is a synthetic rubber that is prepared by solution polymerization of 1,4-butadiene. Its mechanical properties include low temperature flexibility and abrasion resistance. It can be cured by using sulfur based donors and peroxides and thus PB-cis acts as a highly cross-linked polymer with high resilience.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Handbook of Poylmer-Liquid Interaction Parameters and Solubility Parameters (2018)
Morphological, mechanical properties, and fracture behavior of bulk-made ABS resins toughened by high-cis polybutadiene rubber
Yu Z, et al.
Polym. Eng. Sci., 50(5), 961-969 (2010)
Rubber Basics, 80-81 (2002)
Role of the rubber particle and polybutadiene cis content on the toughness of high impact polystyrene
Rovere J, et al.
Journal of materials science & technology, 43(3), 952-959 (2008)
Deniz Turgut et al.
PloS one, 5(12), e15551-e15551 (2010-12-24)
In recent years, there is aroused interest in expressing complex systems as networks of interacting nodes. Using descriptors from graph theory, it has been possible to classify many diverse systems derived from social and physical sciences alike. In particular, folded

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