Skip to Content
Merck
CN
All Photos(1)

Documents

Safety Information

179906

Sigma-Aldrich

Tributylborane solution

1.0 M in THF

Sign Into View Organizational & Contract Pricing
All Photos(1)
Synonym(s):
TBB, Tributylboron
Linear Formula:
[CH3(CH2)3]3B
CAS Number:
122-56-5
Molecular Weight:
182.15
MDL number:
MFCD00009423
UNSPSC Code:
12352001
PubChem Substance ID:
24850833

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.834 g/mL at 25 °C

SMILES string

CCCCB(CCCC)CCCC

InChI

1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI key

CMHHITPYCHHOGT-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Reactant for:
  • Addition reactions for synthesis of phenyltrialkylborate salts
  • Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
  • Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
  • Multicomponent C-alkylation reactions with aromatic aldimines
  • One-pot alkylation-boration and electrophilic substitution

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 1

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C

Regulatory Information

监管及禁止进口产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Yohsuke Taira et al.
Journal of dentistry, 36(8), 595-599 (2008-05-24)
The purpose of the present study was to evaluate the effect of five primers (two sulfur, one phosphate, and two sulfur-phosphate dual-function primers) on the bond strength between a self-curing luting agent and gold-copper-silver (Au-Cu-Ag) alloy. The primers used were
Daisuke Nakayama et al.
The journal of adhesive dentistry, 12(4), 305-310 (2010-02-17)
The purpose of the current study was to evaluate the effect of acidic primers on the bond strength and durability of an acrylic resin luting agent to zirconia. Disk specimens were fabricated from zirconia partially stabilized with yttrium oxide (Katana
Andrew W Bergen et al.
PloS one, 10(7), e0126113-e0126113 (2015-07-02)
The Nicotine Metabolite Ratio (NMR, ratio of trans-3'-hydroxycotinine and cotinine), has previously been associated with CYP2A6 activity, response to smoking cessation treatments, and cigarette consumption. We searched for drug metabolizing enzyme and transporter (DMET) gene variation associated with the NMR
Johanna Claustre et al.
Transplantation, 99(2), 444-450 (2014-08-08)
After lung transplantation (LT), immunoglobulin (Ig) G plasma concentrations<6 g/L are common and correlate with an increased risk of chronic lung allograft dysfunction (CLAD) and a poorer survival. We conducted an open substitution intervention with nonspecific intravenous Ig (IVIg), in
Hiroyasu Koizumi et al.
The journal of adhesive dentistry, 12(3), 215-222 (2010-02-17)
The purpose of the current study was to evaluate the effects of thione and phosphate functional monomers on bond strength and durability of a methacrylic resin luting agent joined to silver-palladium based alloy and titanium. Disk specimens of two different
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service