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Merck
CN

179647

Silver carbonate

99%

Synonym(s):

Disilver carbonate, Fetizon′s reagent, Silver tricarbonate

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About This Item

Linear Formula:
Ag2CO3
CAS Number:
534-16-7
Molecular Weight:
275.75
UNSPSC Code:
12352302
NACRES:
NA.23
PubChem Substance ID:
24850822
EC Number:
208-590-3
Beilstein/REAXYS Number:
6936654
MDL number:
MFCD00003403
Assay:
99%
Form:
powder and chunks

Key Documents

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Product Name

Silver carbonate, 99%

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

SMILES string

[Ag]OC(=O)O[Ag]

assay

99%

form

powder and chunks

reaction suitability

core: silver
reagent type: catalyst

mp

210 °C (dec.) (lit.)

density

6.08 g/mL at 25 °C (lit.)

application(s)

PEM fuel cells
material synthesis precursor

Quality Level

200

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Application

Silver carbonate (Ag2CO3)promotes the regioselective benzylation of carbohydrate derivatives in high yields. Ag2CO3 can be used as a base for the Pd catalysed oxyarylation of olefins by ortho-iodophenols.It can also be used for Koenigs-Knorr glycosylation.

General description

Silver carbonate,prepared by precipitation or ion-exchange method can behave as a visible light sensitive semiconductor photocatalyst.

pictograms

CorrosionEnvironment
GHS05,GHS09

signalword

Danger

hcodes

H318,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW9480
MKCZ2308
MKCW4881
MKCV9026
MKCT1590

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Palladium-catalyzed oxyarylation of olefins using silver carbonate as the base. Probing the mechanism by electrospray ionization mass spectrometry.
Buarque CD, et al.
Journal of Organometallic Chemistry, 695(18), 2062-2067 (2010)
A novel high-efficiency visible-light sensitive Ag 2 CO 3 photocatalyst with universal photodegradation performances: Simple synthesis, reaction mechanism and first-principles study.
Dong H, et al.
Applied Catalysis. B, Environmental, 134, 46-54 (2013)
Photocatalytic behavior and photo-corrosion of visible-light-active silver carbonate/titanium dioxide.
Wang Y, et al
Materials Letters, 115, 85-88 (2014)
Palladium-catalyzed decarboxylative C-H bond arylation of thiophenes.
Peng Hu et al.
Angewandte Chemie (International ed. in English), 51(1), 227-231 (2011-11-17)
José M López-Cepero
The journal of histochemistry and cytochemistry : official journal of the Histochemistry Society, 52(2), 211-216 (2004-01-20)
Silver staining methods, when selective, yield a high-contrast and high-resolution image in optical microscopy. A classical method for silver impregnation of mitochondria has been applied to murine tissues and reveals a marked heterogeneity among mitochondria in single cells. This heterogeneity
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