All Photos(1)
Synonym(s):
Methoxy-2-propanone
Linear Formula:
CH3COCH2OCH3
CAS Number:
Molecular Weight:
88.11
Beilstein:
1560175
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
95%
form
liquid
refractive index
n20/D 1.397 (lit.)
bp
118 °C (lit.)
density
0.957 g/mL at 25 °C (lit.)
SMILES string
COCC(C)=O
InChI
1S/C4H8O2/c1-4(5)3-6-2/h3H2,1-2H3
InChI key
CUZLJOLBIRPEFB-UHFFFAOYSA-N
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General description
The gas-phase basicity of methoxyacetone was studied.
Application
Methoxyacetone was used in the synthesis of doubly borylated enolates.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
Certificates of Analysis (COA)
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Atsushi Abiko et al.
Journal of the American Chemical Society, 124(36), 10759-10764 (2002-09-05)
The novel doubly borylated enolate is identified as an intermediate of the double aldol reaction of acetate esters. As a precursor to the formation of the doubly borylated enolate, carbon-bound boron enolates of carboxylic esters are spectroscopically characterized for the
Guy Bouchoux et al.
The journal of physical chemistry. A, 109(51), 11851-11859 (2005-12-22)
The gas-phase basicities of a representative set of hydroxy- and methoxycarbonyl compounds (hydroxyacetone, 1, 3-hydroxybutanone, 2, 3-hydroxy-3-methylbutanone, 3, 1-hydroxy-2-butanone, 4, 4-hydroxy-2-butanone, 5, 5-hydroxy-2-pentanone, 6, methoxyacetone, 7, 3-methoxy-2-butanone, 8, 4-methoxy-2-butanone, 9, and 5-methoxy-2-pentanone, 10) were experimentally determined by the equilibrium method
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