Skip to Content
Merck
CN
All Photos(2)

Documents

176494

Sigma-Aldrich

Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

Synonym(s):

Eu(facam)3, Eu(tfc)3, Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C36H42EuF9O6
CAS Number:
Molecular Weight:
893.66
EC Number:
MDL number:
UNSPSC Code:
12352115
PubChem Substance ID:
NACRES:
NA.22

optical activity

[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)

technique(s)

NMR: suitable

SMILES string

CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F

InChI

1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;

InChI key

BWIHMSGCCRUUCZ-NCJHBDPTSA-K

Application

Reactant involved in:
  • The synthesis of europium acetylcamphorate phosphine oxide complexes
  • Reactions with 1,10-N,N′-phenanthroline dioxide derivatives
Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Analytical Chemistry, 59, 562-562 (1987)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service