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175595

Sigma-Aldrich

Diethoxydimethylsilane

97%

Synonym(s):

Dimethyldiethoxysilane

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About This Item

Linear Formula:
(CH3)2Si(OC2H5)2
CAS Number:
Molecular Weight:
148.28
Beilstein:
1736110
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

97%

form

liquid

refractive index

n20/D 1.381 (lit.)

bp

114 °C (lit.)

density

0.865 g/mL at 25 °C (lit.)

SMILES string

CCO[Si](C)(C)OCC

InChI

1S/C6H16O2Si/c1-5-7-9(3,4)8-6-2/h5-6H2,1-4H3

InChI key

YYLGKUPAFFKGRQ-UHFFFAOYSA-N

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General description

Diethoxydimethylsilane (DEDMS) is an organically modified silicate (ORMOSIL) with two methyl groups in each unit that facilitate the hydrophobic characteristics. It is mainly utilized to functionalize a variety of substrates.

Application

Diethoxydimethylsilane (DMDES) may be used to modify epoxy resin6 and the surfaces of pure silica and Pd/SiO2 hydrogen gas sensors. Surface modification results in enhanced gas sensing properties of the sensors. {43}-{44}Diethoxydimethylsilane may be used as a precursor for the synthesis of ultrafine SiC powder. {45} Studies report its use as a precursor for ORMOSIL (Organically modified SILicates) and thin a-SiOxCyHz films.{47}
The composite of DEDMS and triethoxymethylsilane can be used to synthesize a liquid precursor resin for the preparation of silicon oxycarbide (SiOC). It can form a sol-gel coating on polyamide-polyethylene (PA/PE), which can be used as an anti-oxidizing food packaging material. It can also be used as a precursor in the synthesis of polydimethylsiloxane, which forms an anti-corrosive coating composite with waterborne polyurethane.

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

WGK

WGK 2

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Control of water-channel structure and state of water in sulfonated poly (arylene ether sulfone)/diethoxydimethylsilane in situ hybridized proton conductors and its influence on transport properties for DMFC membranes.
So SY, et al.
Journal of Membrane Science, 346(1), 131-135 (2010)
Organic/inorganic thin films deposited from diethoxydimethylsilane by plasma enhanced chemical vapor deposition
Roualdes S, et al.
Journal of Non-Crystalline Solids, 248(2-3), 235-246 (1999)
Preparation of finely macroporous SiOC foams with high mechanical properties and with hierarchical porosity via pyrolysis of a siloxane/epoxide composite.
Strachota A, et al.
Ceramics International, 41(7), 8402-8410 (2015)
Carbon dioxide laser synthesis of ultrafine silicon carbide powders from diethoxydimethylsilane.
Li, Ya-Li, et al.
Journal of the American Ceramic Society. American Ceramic Society, 77(6), 1662-1664 (1994)
Surface Modification of Sol-Gel Hybrid films using fluorinated silica nanoparticles
Purcar, V., Donescu, D., Spataru, I. C., Ghiurea, M., Caprarescu, S., Petcu, C., & Nistor
Rev. Roum. Chim., 58(1), 37-42 (2013)

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