164798
Trifluoromethanesulfonyl chloride
≥99%
Synonym(s):
Triflyl chloride
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About This Item
Linear Formula:
CF3SO2Cl
CAS Number:
Molecular Weight:
168.52
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-009-0
Beilstein/REAXYS Number:
1812106
MDL number:
Product Name
Trifluoromethanesulfonyl chloride, ≥99%
InChI key
GRGCWBWNLSTIEN-UHFFFAOYSA-N
InChI
1S/CClF3O2S/c2-8(6,7)1(3,4)5
SMILES string
FC(F)(F)S(Cl)(=O)=O
vapor pressure
10.36 psi ( 20 °C)
assay
≥99%
form
liquid
refractive index
n20/D 1.334 (lit.)
bp
29-32 °C (lit.)
density
1.583 g/mL at 25 °C (lit.)
functional group
fluoro
storage temp.
2-8°C
Quality Level
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Application
Trifluoromethanesulfonyl chloride can be used as:
- A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
- A sulfonating agent for alcohols.
- A chlorinating agent for carbanions.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles
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Journal of the Chemical Society. Perkin Transactions 1, 627-627 (1991)
Marleen Häring et al.
The Journal of organic chemistry, 83(15), 7928-7938 (2018-05-29)
In this work, we demonstrate that useful C-C bond-forming photoredox catalysis can be performed in air using easily prepared gel networks as reaction media to give similar results as are obtained under inert atmosphere conditions. These reactions are completely inhibited
Journal of the Chemical Society. Perkin Transactions 1, 1339-1339 (1994)
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