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163694

Sigma-Aldrich

2,4,6-Tribromoaniline

98%

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Linear Formula:
Br3C6H2NH2
CAS Number:
147-82-0
Molecular Weight:
329.81
Beilstein:
2209258
EC Number:
205-700-1
MDL number:
MFCD00007634
UNSPSC Code:
12352100
PubChem Substance ID:
24850033
NACRES:
NA.22

Assay

98%

form

powder

bp

300 °C (lit.)

mp

120-122 °C (lit.)

solubility

alcohol: soluble (cold)(lit.)
alcohol: soluble (hot)(lit.)
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)

SMILES string

Nc1c(Br)cc(Br)cc1Br

InChI

1S/C6H4Br3N/c7-3-1-4(8)6(10)5(9)2-3/h1-2H,10H2

InChI key

GVPODVKBTHCGFU-UHFFFAOYSA-N

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General description

Electrochemical oxidation of 2,4,6-tribromoaniline in aqueous sulphuric acid solutions at platinum electrode has been studied by rotating disc electrode and cyclic voltammetry. 2,4,6-Tribromoaniline on closed-tube pyrolysis yields polybromophenazines. It is an intermediate in the formulation of flame retardants incorporated to plastic materials.

Application

2,4,6-Tribromoaniline was used in simultaneous determination of phenolic brominated flame retardants and their by-products in water.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H317,H319,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

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Voltammetric study of the oxidation kinetics of 2, 4, 6,-tribromoaniline in acid medium.
Brillas E, et al.
J. Electroanal. Chem. Interfac. Electrochem., 160(1), 185-198 (1984)
Formation of bromodioxin analogs from closed tube pyrolysis of 2, 4, 6-tribromoaniline (I).
Alsabbagh AM, et al.
Chemosphere, 17(12), 2391-2396 (1988)
P López et al.
Journal of chromatography. A, 1216(3), 334-345 (2008-09-03)
Brominated flame retardants (BFRs) are the chemicals of high importance within the REAch framework. In addition to polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA), other BFRs such as bromophenols, intermediates in FR formulation like bromoanilines, and their

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