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About This Item
Linear Formula:
HCSN(CH3)2
CAS Number:
Molecular Weight:
89.16
Beilstein:
1737191
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
≥98%
form
liquid
refractive index
n20/D 1.576 (lit.)
bp
58-60 °C/1 mmHg (lit.)
density
1.047 g/mL at 25 °C (lit.)
SMILES string
[H]C(=S)N(C)C
InChI
1S/C3H7NS/c1-4(2)3-5/h3H,1-2H3
InChI key
SKECXRFZFFAANN-UHFFFAOYSA-N
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General description
N,N-Dimethylthioformamide undergoes desulfurization reaction with hydrosilane under photo irradiation in the presence of a methyl iron complex. It forms a deep-orange complex with anhydrous bismuth(III) trifluoromethanesulfonate.
Application
N,N-Dimethylthioformamide was used as sulfur donor solvent to investigate the coordination chemistry of lead(II).
WGK
WGK 3
Flash Point(F)
210.2 °F
Flash Point(C)
99 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Krzysztof Lyczko et al.
Inorganic chemistry, 43(22), 7094-7100 (2004-10-27)
At the dissolution of anhydrous bismuth(III) trifluoromethanesulfonate in N,N-dimethylthioformamide (DMTF) a deep red-orange complex, lambda(max) = 457 nm, is formed. Bismuth(III) is reduced by the solvent to a low-valent oxidation state stabilized by the sulfur-coordinating solvent DMTF. The obtained complex
Kozo Fukumoto et al.
Chemical communications (Cambridge, England), 48(32), 3809-3811 (2012-01-06)
Desulfurization of N,N-dimethylthioformamide (Me(2)NCHS) by hydrosilane has been achieved under photo irradiation in the presence of a methyl iron complex. The reaction sequences have been proposed, in which silyl migration from Fe to S of thioformamide triggers the cleavage of
Ingmar Persson et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 22(51), 18583-18592 (2016-11-20)
The coordination chemistry of d10 s2 metal ions is strongly affected by an (at least partially) occupied d10 s2 metal ion-ligand atom antibonding orbital, which may cause a void in the coordination sphere due to repulsion between the electrons in
Ingmar Persson et al.
Inorganic chemistry, 50(3), 1058-1072 (2011-01-14)
The coordination chemistry of lead(II) in the oxygen donor solvents water, dimethylsulfoxide (dmso, Me(2)SO), N,N-dimethylformamide (dmf), N,N-dimethylacetamide (dma), N,N'-dimethylpropyleneurea (dmpu), and 1,1,3,3-tetramethylurea (tmu), as well as in the sulfur donor solvent N,N-dimethylthioformamide (dmtf), has been investigated by extended X-ray absorption
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