162310
3-Fluoroanisole
99%
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About This Item
Linear Formula:
FC6H4OCH3
CAS Number:
Molecular Weight:
126.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-267-4
MDL number:
Product Name
3-Fluoroanisole, 99%
InChI key
MFJNOXOAIFNSBX-UHFFFAOYSA-N
InChI
1S/C7H7FO/c1-9-7-4-2-3-6(8)5-7/h2-5H,1H3
SMILES string
COc1cccc(F)c1
assay
99%
form
liquid
refractive index
n20/D 1.488 (lit.)
bp
158 °C/743 mmHg (lit.)
density
1.104 g/mL at 25 °C (lit.)
functional group
fluoro
Quality Level
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Application
3-Fluoroanisole was used in the synthesis of 4-fluoro-5,6-dihydroxytryptamine. It was also used in the synthesis of 3-fluoro- and 5-fluoronoradrenaline.
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Synthesis and EPR investigations of fluorocatecholamines.
Stegmann HB, et al.
Journal of the Chemical Society. Perkin Transactions 1, 2(3), 547-555 (1994)
M Kawase et al.
Journal of medicinal chemistry, 33(8), 2204-2211 (1990-08-01)
The 5,6-dihydroxytryptamine (5,6-DHT) derivatives 4-fluoro- and 7-fluoro-5,6-DHTs (26a,b) and 4,7-difluoro-5,6-DHT (26c) were synthesized from 3-fluoroanisole (1) and 1,4-difluoro-2,3-dimethoxybenzene (13), respectively. Efficient methods were developed for the conversion of 1 to 4-fluoro- and 7-fluoro-5,6-bis(benzyloxy)indoles (12a,b, respectively), and 13 to 4,7-difluoro-5,6-[( diphenylmethylene)dioxy]indole
Oriol Planas et al.
Science (New York, N.Y.), 367(6475), 313-317 (2020-01-18)
Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo oxidative addition, reductive elimination, and transmetallation in a manner
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