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16230

Sigma-Aldrich

4-Bromoaniline

≥99.0% (GC)

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Synonym(s):
1-Amino-4-bromobenzene, p-Bromoaniline
Linear Formula:
BrC6H4NH2
CAS Number:
106-40-1
Molecular Weight:
172.02
Beilstein:
742031
EC Number:
203-393-9
MDL number:
MFCD00007822
UNSPSC Code:
12352100
PubChem Substance ID:
329751153
NACRES:
NA.22

Quality Level

100

Assay

≥99.0% (GC)

form

solid

mp

56-62 °C (lit.)
63-65 °C

solubility

ethanol: soluble 0.5 g/10 mL, clear, colorless to almost colorless

SMILES string

Nc1ccc(Br)cc1

InChI

1S/C6H6BrN/c7-5-1-3-6(8)4-2-5/h1-4H,8H2

InChI key

WDFQBORIUYODSI-UHFFFAOYSA-N

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General description

Photocatalytic degradation of 4-bromoaniline over ZnO or TiO2 (anatase and rutile) has been investigated in a photocatalytic reactor.

Application

4-Bromoaniline was used as carbon and nitrogen supplement in the culture medium of Moraxella sp. strain G.

Biochem/physiol Actions

4-Bromoaniline reduces gluconeogenesis in renal cortical slices obtained from the kidneys of untreated, male Fischer 344 rats.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

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Mohammad Hossein Habibi et al.
Annali di chimica, 94(5-6), 421-428 (2004-07-29)
Photocatalytic degradation of aqueous solution of aniline derivatives such as ortho-nitroaniline (ONA), meta-nitroaniline (MNA), para-nitroaniline (PNA), 4-bromoaniline (4-BrA) and 2-chloroaniline (2-ClA) were carried out over ZnO or TiO2 (anatase and rutile) in a photocatalytic reactor. The observed results revealed that
Fernanda Raphael Escobar Gimenes et al.
PloS one, 15(11), e0241849-e0241849 (2020-11-20)
To identify the types of nasogastric/nasoenteric tube (NGT/NET)-related adverse events and to analyze the degree of harm and the factors associated with mechanical device-related complications. A prospective cohort study was conducted from October 2017 to April 2019 in seven Brazilian
S K Hong et al.
Toxicology letters, 114(1-3), 125-133 (2000-03-14)
Haloanilines are widely used as chemical intermediates in the manufacture of pesticides, dyes and drugs. The purpose of this study was to examine the in vitro nephrotoxic effects of the four 4-haloaniline and four 3,5-dihaloaniline isomers using renal cortical slices
H Major et al.
Xenobiotica; the fate of foreign compounds in biological systems, 33(8), 855-869 (2003-08-26)
1. The metabolic fate of 4-bromoaniline (4-BrA) was investigated in rat following intraperitoneal administration at 50 mg kg(-1) using HPLC-TOF-MS/MS. 2. The sensitivity provided by the use of TOF-MS/MS, aided by the distinctive isotope pattern resulting from the presence of
J Zeyer et al.
Applied and environmental microbiology, 50(2), 447-453 (1985-08-01)
Moraxella sp. strain G is able to utilize as sole source of carbon and nitrogen aniline, 4-fluoroaniline, 2-chloroaniline, 3-chloroaniline, 4-chloroaniline (PCA), and 4-bromoaniline but not 4-iodoaniline, 4-methylaniline, 4-methoxyaniline, or 3,4-dichloroaniline. The generation time on PCA was 6 h. The pathway
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