161411
α-Chlorocinnamaldehyde
97%
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About This Item
Linear Formula:
C6H5CH=C(Cl)CHO
CAS Number:
Molecular Weight:
166.60
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
242-237-4
MDL number:
Assay:
97%
Form:
liquid
InChI key
SARRRAKOHPKFBW-TWGQIWQCSA-N
InChI
1S/C9H7ClO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-7H/b9-6-
SMILES string
Cl\C(C=O)=C/c1ccccc1
assay
97%
form
liquid
refractive index
n20/D 1.64 (lit.)
bp
107-108 °C/3 mmHg (lit.)
mp
20-22 °C (lit.)
storage temp.
2-8°C
General description
α-Chlorocinnamaldehyde inhibits the corrosion of ARMCO iron in 4 M HCl. It undergoes chemoselective reduction in the presence of calcium amidoborane to yield allylic alcohol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Iron corrosion inhibition in hot 4 M HCl solution by t-cinnamaldehyde and its structure-related compounds.
Zucchi F, et al.
Corrosion Science, 36(10), 1683-1690 (1994)
Calcium amidoborane, a new reagent for chemoselective reduction of a, ?-unsaturated aldehydes and ketones to allylic alcohols.
Xu W, et al.
Royal Society of Chemistry Advances, 2(14), 6005-6010 (2012)
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