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Key Documents

Safety Information

159301

Sigma-Aldrich

3,4-Dichloro-1-butene

98%

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About This Item

Linear Formula:
ClCH2CH(Cl)CH=CH2
CAS Number:
Molecular Weight:
125.00
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

vapor density

4.31 (vs air)

vapor pressure

17 mmHg ( 25 °C)

Assay

98%

refractive index

n20/D 1.4658 (lit.)

bp

123 °C (lit.)

mp

−61 °C (lit.)

density

1.15 g/mL at 25 °C (lit.)

SMILES string

ClCC(Cl)C=C

InChI

1S/C4H6Cl2/c1-2-4(6)3-5/h2,4H,1,3H2

InChI key

XVEASTGLHPVZNA-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

82.4 °F - closed cup

Flash Point(C)

28 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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P A Bakalian et al.
Voprosy pitaniia, (5)(5), 68-71 (1987-09-01)
It was shown experimentally that alimentary prevention of dichlorobutene intoxication could be realized in the presence of a protein-enriched ration, through additional injections of nutrients possessing antioxidant and lipotropic properties and playing a pathogenetically valid protective role in this intoxication.
Andrew F M Johnstone et al.
Toxicology in vitro : an international journal published in association with BIBRA, 69, 104989-104989 (2020-09-04)
The Hard-Soft Acid and Base hypothesis can be used to predict the potential bio-reactivity (electrophilicity) of a chemical with intracellular proteins, resulting in neurotoxicity. Twelve chemicals predicted to be neurotoxic were evaluated in vitro in rat dorsal root ganglia (DRG)
[Experimental establishment of the maximum permissible concentration of 1,4- and 3,4-dichlorobutenes in reservoir water].
M S Gizhlarian et al.
Gigiena i sanitariia, (7)(7), 77-78 (1986-07-01)
[Nephrotoxic action of dichlorobutenes].
F R Petrosian et al.
Gigiena truda i professional'nye zabolevaniia, (3)(3), 44-45 (1985-03-01)
N A Hamill et al.
Environmental science & technology, 35(13), 2823-2827 (2001-07-17)
Gas-phase photocatalysis of 1,4-dichlorobut-2-enes and 3,4-dichlorobut-1-ene (DCB) has been studied using TiO2 and 3% WO3/TiO2 supported on SiO2. DCB was found to oxidize efficiently over these catalysts; however, only low rates of CO2 formation were observed. With these chlorinated hydrocarbons

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