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Merck
CN

158402

Dicyclohexano-18-crown-6

98%

Synonym(s):

2,3,11,12-Dicyclohexano-1,4,7,10,13,16-hexaoxacyclooctadecane, 2,5,8,15,18,21-Hexaoxatricyclo[20.4.0.09.14]hexacosane, Dicyclohexyl-18-crown-6, Perhydro-dibenzo-18-crown-6

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About This Item

Empirical Formula (Hill Notation):
C20H36O6
CAS Number:
16069-36-6
Molecular Weight:
372.50
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
24849733
EC Number:
240-216-4
Beilstein/REAXYS Number:
1130529
MDL number:
MFCD00005099
Assay:
98%
Form:
solid

Key Documents

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InChI key

BBGKDYHZQOSNMU-UHFFFAOYSA-N

InChI

1S/C20H36O6/c1-2-6-18-17(5-1)23-13-9-21-11-15-25-19-7-3-4-8-20(19)26-16-12-22-10-14-24-18/h17-20H,1-16H2

SMILES string

C1CCC2OCCOCCOC3CCCCC3OCCOCCOC2C1

assay

98%

form

solid

Quality Level

200

reaction suitability

core: crown ether

functional group

ether

Related Categories

Application

Anion activator, and complexing agent which solubilizes alkali metal ions in non-polar solvents.

hcodes

H301,H319

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP7143
SHBM3571
SHBM6110
SHBM3173
SHBK2833

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Gang Ye et al.
Journal of hazardous materials, 225-226, 8-14 (2012-05-23)
A novel kind of polysiloxane resin functionalized with dicyclohexano-18-crown-6 (DCH18C6) was synthesized through a post-modification approach. The DCH18C6 moieties bearing amino groups were firstly prepared, followed by covalent grafting to a silica precursor P-(CH(2))(3)-Cl (Where P represents a 3-dimentional polymerized
H Breitbart et al.
Molecular biology reports, 6(4), 195-198 (1980-12-31)
Valinomycin blocks protein synthesis at the elongation stage in intact reticulocyte while being without action on a cell free system. We demonstrate here that this membrane mediated inhibition is accompanied by a change of the energy charge (ATP/ADP/AMP ratio) of
Toshiyuki Fujii et al.
The journal of physical chemistry. A, 114(7), 2543-2552 (2010-02-04)
This work reports on the chemical isotope fractionation of Zn(II) by a solvent extraction method with the crown ether dicyclohexano-18-crown-6. The (m)Zn/(64)Zn ratios (m = 66, 67, and 68) were analyzed by multiple-collector inductively coupled plasma mass spectrometry. The relative
Mahmoud Chamsaz et al.
Journal of hazardous materials, 167(1-3), 597-601 (2009-02-24)
A simple single drop liquid-phase microextraction (SDME) technique, combined with electrothermal atomic absorption spectroscopy (ETAAS) is developed both to preconcentrate and determine thallium (I) ions in aqueous solutions. The ions were transferred from 10.0 ml of aqueous sample (donor phase)
Radioiodination of alkyl halides with Na 125I catalyzed by dicyclohexyl-18-crown-6.
L Bo-Li et al.
Radioisotopes, 30(7), 391-393 (1981-07-01)
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