15587
Borane dimethyl sulfide complex
technical, >90% in dimethyl sulfide
Synonym(s):
BMS, Borane methyl sulfide complex, Dimethyl sulfide borane, Trihydro[thiobis[methane]]boron
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About This Item
Linear Formula:
(CH3)2S · BH3
CAS Number:
Molecular Weight:
75.97
Beilstein:
3663489
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
Recommended Products
grade
technical
reaction suitability
reagent type: reductant
concentration
>90% in dimethyl sulfide
density
0.801 g/mL at 20 °C (lit.)
storage temp.
2-8°C
SMILES string
B.CSC
Application
Reactant used as a regioselective reducing agent
Reactant involved in:
Reactant involved in:
- Hydroboration / oxidation
- Synthesis of cage compounds
Other Notes
Convenient and stable source of borane for hydroborations, reviews ; Selective reduction of α-hydroxyesters
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Water-react 1
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
64.4 °F
Flash Point(C)
18 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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S. Saito et al.
Chemistry Letters (Jpn), 1389-1389 (1984)
R.O. Hutchins et al.
Organic preparations and procedures international, 13, 225-225 (1981)
H.C. Brown et al.
The Journal of Organic Chemistry, 47, 3153-3153 (1982)
S. Krishnamurthy
Tetrahedron Letters, 23, 3315-3315 (1982)
Elin S Gray et al.
Oncotarget, 6(39), 42008-42018 (2015-11-03)
Repeat tumor biopsies to study genomic changes during therapy are difficult, invasive and data are confounded by tumoral heterogeneity. The analysis of circulating tumor DNA (ctDNA) can provide a non-invasive approach to assess prognosis and the genetic evolution of tumors
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