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Safety Information

151823

Sigma-Aldrich

Chloroform-d

99.8 atom % D

Synonym(s):

Deuterochloroform

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Select a Size

10 X 0.75 ML
CN¥313.32
10 X 0.6 ML
CN¥351.61
10 X 1 ML
CN¥418.02
50 G
CN¥444.27
100 G
CN¥742.43
250 G
CN¥1,536.78
1 KG
CN¥4,319.17

CN¥313.32

Available to ship onApril 17, 2025Details

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10 X 0.75 ML
CN¥313.32
10 X 0.6 ML
CN¥351.61
10 X 1 ML
CN¥418.02
50 G
CN¥444.27
100 G
CN¥742.43
250 G
CN¥1,536.78
1 KG
CN¥4,319.17

About This Item

Linear Formula:
CDCl3
CAS Number:
865-49-6
Molecular Weight:
120.38
Beilstein:
1697633
EC Number:
212-742-4
MDL number:
MFCD00000827
UNSPSC Code:
12142201
PubChem Substance ID:
24849167
NACRES:
NA.21

CN¥313.32

Available to ship onApril 17, 2025Details

Request a Bulk Order

isotopic purity

99.8 atom % D

Quality Level

200

Assay

≥99% (CP)

form

liquid

technique(s)

NMR: suitable

refractive index

n20/D 1.444 (lit.)

bp

60.9 °C (lit.)

mp

−64 °C (lit.)

density

1.500 g/mL at 25 °C (lit.)

mass shift

M+1

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Show Differences

1 of 4

This Item
494275151858612200
Chloroform-d 99.8 atom % D

151823

Chloroform-d

Chloroform-d "100%", 99.96 atom % D, contains 0.03 % (v/v) TMS

494275

Chloroform-d

Chloroform-d "100%", 99.95 atom % D

151858

Chloroform-d

Chloroform-d 99.8 atom % D, contains 0.05 % (v/v) TMS

612200

Chloroform-d

mass shift

M+1

mass shift

M+1

mass shift

M+1

mass shift

M+1

assay

≥99% (CP)

assay

≥99.00%

assay

≥99% (CP)

assay

≥99% (CP)

technique(s)

NMR: suitable

technique(s)

NMR: suitable

technique(s)

NMR: suitable

technique(s)

NMR: suitable

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

General description

Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a standard purity solvent for NMR (Nuclear Magnetic Resonance) analyses. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported.[1][2] Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the ν1 and ν2 bands of CHCl3 and CDCl3.[3]

Application

Chloroform-d has been employed as solvent in a 1H NMR (Proton Nuclear Magnetic Resonance) spectroscopic study.[4] It has been employed as solvent during the 31PNMR (Phosphorus-31 nuclear magnetic resonance) spectral investigation of triphenyl phosphate and tris(2-chloroethyl) phosphate.[5] It has also been used as the deuterated solvent in the 1H NMR spectral studies of 2-(4-bromobenzyl)-3-hydroxypropanoic acid and 3-hydroxy-2-(4-methoxybenzyl)propanoic acid.[6] It has also been used as the deuterated solvent for the 1HNMR spectral studies of 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxy-phenyl) hexafluoropropane dianhydride (6FDA) polyimide.[7]

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Pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

Target Organs

Central nervous system, Liver,Kidney

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

does not flash

Flash Point(C)

does not flash

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

美国出口管控1C298产品
危险化学品
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    Lot/Batch Number
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    0000441656
    MKCT3613
    0000441656
    0000441655

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    Selective synthesis of 3-hydroxy acids from Meldrum's acids using SmI2-H2O
    Szostak M, et al.
    Nature Protocols, 7(5), 970-977 (2012)
    Hyunwoo Joo et al.
    Science advances, 7(1) (2021-02-02)
    Personalized biomedical devices have enormous potential to solve clinical challenges in urgent medical situations. Despite this potential, a device for in situ treatment of fatal seizures using pharmaceutical methods has not been developed yet. Here, we present a novel treatment
    Method development in quantitative NMR towards metrologically traceable organic certified reference materials used as 31P qNMR standards.
    Weber M, et al.
    Analytical and Bioanalytical Chemistry, 407(11), 3115-3123 (2015)
    Gas sorption and characterization of thermally rearranged polyimides based on 3, 3'-dihydroxy-4, 4'-diamino-biphenyl (HAB) and 2, 2'-bis-(3, 4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA)
    Smith.PZ, et al.
    Journal of Membrane Science, 415, 558-567 (2012)
    Xuejun Liu et al.
    Nature protocols, 2(5), 1288-1296 (2007-06-05)
    A nearly quantitative 18-component synthesis of a nanocontainer, which is built up from six bowl-shaped cavitands that are connected together with 12 -CH=N-CH2CH2-N=CH- linkers, and its subsequent reduction are described. This nanocontainer has an estimated cavity volume of 1,700 A3
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