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Merck
CN

148245

2-Methoxynaphthalene

99%

Synonym(s):

Methyl 2-naphthyl ether

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About This Item

Linear Formula:
C10H7OCH3
CAS Number:
93-04-9
Molecular Weight:
158.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24848894
EC Number:
202-213-6
Beilstein/REAXYS Number:
1859408
MDL number:
MFCD00004061
Assay:
99%

Key Documents

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mp

70-73 °C (lit.)

solubility

benzene: soluble, carbon disulfide: soluble, diethyl ether: soluble

density

1.064 g/mL at 25 °C (lit.)

InChI key

LUZDYPLAQQGJEA-UHFFFAOYSA-N

InChI

1S/C11H10O/c1-12-11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3

SMILES string

COc1ccc2ccccc2c1

assay

99%

bp

274 °C (lit.)

Quality Level

100

Gene Information

human ... CYP1A2(1544)

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Application

2-methoxynaphthalene acylation was used as a model reaction to study the catalytic benefits of delamination. It was also used to study the alkali-metal-mediated manganation (AMMMn) reactions.

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

hcodes

H319,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL3505
MKCB1253V
MKBN2593V
MKBK3623V
STBC7229V

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Victoria L Blair et al.
Inorganic chemistry, 48(18), 8863-8870 (2009-09-15)
Alkali-metal-mediated manganation (AMMMn) reactions of the synergic base sodium monoalkyl-bisamidomanganate [(tmeda)Na(tmp)(CH(2)SiMe(3))Mn(tmp)] (1) with naphthalene, 1-methoxynaphthalene, or 2-methoxynaphthalene are reported. These novel direct manganation [Mn(II)] reactions produced the crystalline ortho-manganated naphthyl products [(tmeda)Na(tmp)(2-C(10)H(7))Mn(tmp)] (3), [(tmeda)Na(tmp){2-(1-MeOC(10)H(6))}Mn(CH(2)SiMe(3))] (4), and [(tmeda)Na(tmp){3-(2-MeOC(10)H(6))}Mn(tmp)] (5) in reasonable
Xiaoying Ouyang et al.
Journal of the American Chemical Society, 136(4), 1449-1461 (2013-12-19)
Layered borosilicate zeolite precursor ERB-1P (Si/B = 11) is delaminated via isomorphous substitution of Al for B using a simple aqueous Al(NO3)3 treatment. Characterization by PXRD shows loss of long-range order, and TEM demonstrates transformation of rectilinear layers in the
G M Whited et al.
Bioorganic & medicinal chemistry, 2(7), 727-734 (1994-07-01)
2-Methoxynaphthalene was subjected to biooxidation by whole cells of six organisms: Pseudomonas putida F39/D containing toluene dioxygenase, Escherichia coli JM109(pDTG601), containing recombinant toluene dioxygenase from Pp F39/D, Pseudomonas sp. NCIB 9816/11, containing naphthalene dioxygenase. E. coli JM109(pDTG141), containing recombinant naphthalene
P Di Gennaro et al.
Biotechnology and bioengineering, 93(3), 511-518 (2005-09-30)
The bioconversion of naphthalene to the 1,2-dihydro-1,2-dihydroxy derivative was performed in good yield using an Escherichia coli recombinant strain carrying Pseudomonas fluorescens N3 dioxygenase. However, the efficiency of such transformation is affected by many process parameters, and their optimization is
R R Price et al.
Journal of microencapsulation, 10(2), 215-222 (1993-04-01)
Many natural products that exhibit biocidal activity have poor solubility in water. In order to explore the prolonged delivery of these compounds from microtubules we have utilized 2-methoxynaphthalene as a model to elucidate release characteristics of hydrophobic compounds entrapped in
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