All Photos(2)
Synonym(s):
β-Bromopropanoyl chloride, β-Bromopropionyl chloride, ψ-Bromopropanoyl chloride, 3-Bromopropanoic acid chloride, 3-Bromopropanoyl chloride
Linear Formula:
BrCH2CH2COCl
CAS Number:
Molecular Weight:
171.42
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical grade
Quality Level
form
liquid
refractive index
n20/D 1.49 (lit.)
bp
55-57 °C/17 mmHg (lit.)
density
1.701 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
ClC(=O)CCBr
InChI
1S/C3H4BrClO/c4-2-1-3(5)6/h1-2H2
InChI key
IHBVNSPHKMCPST-UHFFFAOYSA-N
Related Categories
General description
3-Bromopropionyl chloride reacts with poly(ethylene glycol) methacrylate to yield brominated poly(ethylene glycol) methacrylate. It causes the acylation of 4-aryl-substituted 3,4-di-hydropyrimidine(1H)-2-thiones to give bicyclic pyrimido[2,1-b][1,3]thiazines.
Application
3-Bromopropionyl chloride was used in the preparation of 1-chloro-4-bromo-2-butanone.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Synthesis and Characterization of a Novel Macromonomer Initiator for Reversible Addition Fragmentation Chain Transfer (RAFT). Evaluation of the Polymerization Kinetics and Gelation Behaviors.
Ozturk T and Hazer B.
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 47(3), 265-272 (2010)
Synthesis of bicyclic pyrimido [2, 1-b][1, 3] thiazines based on 3, 4-dihydropyrimidine-(1H)-2-thiones.
Kulakov IV and Turdybekov DM.
Chemistry of Heterocyclic Compounds, 46(3), 342-346 (2010)
A Nagy et al.
Proceedings of the National Academy of Sciences of the United States of America, 93(6), 2464-2469 (1996-03-19)
A convenient, high yield conversion of doxorubicin to 3'-deamino-3'-(2''-pyrroline-1''-yl)doxorubicin is described. This daunosamine-modified analog of doxorubicin is 500-1000 times more active in vitro than doxorubicin. The conversion is effected by using a 30-fold excess of 4-iodobutyraldehyde in anhydrous dimethylformamide. The
Ji Eon Chae et al.
Polymers, 13(5) (2021-03-07)
Polystyrene-based polymers with variable molecular weights are prepared by radical polymerization of styrene. Polystyrene is grafted with bromo-alkyl chains of different lengths through Friedel-Crafts acylation and quaternized to afford a series of hydroxide-ion-conducting ionomers for the catalyst binder for the
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