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1-Cyano-4-fluorobenzene, 4-Cyanofluorobenzene, 4-Fluorobenzonitrile, 4-Fluorocyanobenzene, Para-fluorobenzonitrile, p-Cyanofluorobenzene, p-Fluorobenzonitrile, p-Fluorophenyl cyanide
FC6H4CN
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Quality Level
Assay
99%
form
solid
bp
188 °C/750 mmHg (lit.)
mp
32-34 °C (lit.)
SMILES string
Fc1ccc(cc1)C#N
InChI
1S/C7H4FN/c8-7-3-1-6(5-9)2-4-7/h1-4H
InChI key
AEKVBBNGWBBYLL-UHFFFAOYSA-N
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General description
4-Fluorobenzonitrile undergoes metal-mediated coupling to yield eight-membered thorium(IV) tetraazamacrocycle. It undergoes condensation with diphenylamine to yield monomer 4-cyanotriphenylamine.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Sol. 1
WGK
WGK 3
Flash Point(F)
149.0 °F
Flash Point(C)
65 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Chemical communications (Cambridge, England), (10)(10), 1029-1031 (2007-02-28)
An eight-membered thorium(IV) tetraazamacrocycle is produced by the sequential, metal-mediated coupling of four equivalents of 4-fluorobenzonitrile; its formation is consistent with the involvement of an imido intermediate, generated from a thorium ketimide complex.
Poly (triphenylamine) s derived from oxidative coupling reaction: Substituent effects on the polymerization, electrochemical, and electro-optical properties.
Journal of Polymer Science Part A: Polymer Chemistry, 47(1), 285-294 (2009)
Chemistry (Weinheim an der Bergstrasse, Germany), 24(45), 11771-11778 (2018-05-29)
Fluorous organic building blocks were utilized to develop two self-assembled, hydrophobic, fluorinated porous organic polymers (FPOPs), namely, FPOP-100 and FPOP-101. Comprehensive mechanical analyses of these functionalised triazine network polymers marked the introduction of mechanical stiffness among all porous organic network
Science (New York, N.Y.), 367(6475), 313-317 (2020-01-18)
Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo oxidative addition, reductive elimination, and transmetallation in a manner
Molecules (Basel, Switzerland), 24(7) (2019-04-17)
Imaging techniques, such as positron emission tomography (PET), represent great progress in the clinical development of drugs and diagnostics. However, the efficient and timely synthesis of appropriately labeled compounds is a largely unsolved problem. Numerous small drug-like molecules with high
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