123579
Benzenesulfinic acid sodium salt
98%
Synonym(s):
Sodium benzenesulfinate
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
C6H5SO2Na
CAS Number:
Molecular Weight:
164.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-842-8
Beilstein/REAXYS Number:
3598405
MDL number:
Product Name
Benzenesulfinic acid sodium salt, 98%
InChI key
CHLCPTJLUJHDBO-UHFFFAOYSA-M
InChI
1S/C6H6O2S.Na/c7-9(8)6-4-2-1-3-5-6;/h1-5H,(H,7,8);/q;+1/p-1
SMILES string
[Na+].[O-]S(=O)c1ccccc1
assay
98%
form
solid
mp
>300 °C (lit.)
functional group
sulfinic acid
Quality Level
Related Categories
Application
Benzenesulfinic acid sodium salt has been used in synthesis of sulfones by reaction of organic halides and sodium benzenesulfinate using higher alcohols or diols as solvents.It was also used in the synthesis of aryl sulfones via copper-catalyzed cross-coupling with boronic acids and vinyl sulfones via reaction with vicinal dibromides.
General description
Benzenesulfinic acid sodium salt when treated with alkynylselenonium salts yields (Z)-β-alkoxyvinylsulfones. It undergoes rhodium-catalyzed desulfinative coupling with aldehydes to yield ketones.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Synthesis, 1465-1465 (2007)
Reactions of alkynylselenonium salts with sodium benzenesulfinate.
Kataoka T, et al.
Tetrahedron Letters, 38(10), 1809-1812 (1997)
Sulfones from sodium benzenesulfinate.
Kauffman JM.
Journal of Chemical and Engineering Data, 14(4), 498-499 (1969)
Rhodium-Catalyzed Aerobic Coupling between Aldehydes and Arenesulfinic Acid Salts: A Novel Synthesis of Aryl Ketones.
Rao H, et al.
Advanced Synthesis & Catalysis, 353(10), 1701-1706 (2011)
Pedro Paulo Albuquerque Cavalcanti Albuquerque et al.
The journal of adhesive dentistry, 21(2), 133-141 (2019-04-06)
To determine the degree of conversion (DC), physicochemical properties, and microshear bond strength (µSBS) of experimental self-adhesive resin cements (SARCs) to dentin and yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) ceramic. Dual-curing cements were formulated with UDMA, HEMA, bis-GMA, and TEG-DMA as
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service