117374
4′-Methoxyacetophenone
99%
Synonym(s):
4-Acetylanisole
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About This Item
Linear Formula:
CH3OC6H4COCH3
CAS Number:
Molecular Weight:
150.17
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39023808
UNSPSC Code:
12352100
EC Number:
202-815-9
MDL number:
Beilstein/REAXYS Number:
742313
Product Name
4′-Methoxyacetophenone, 99%
InChI key
NTPLXRHDUXRPNE-UHFFFAOYSA-N
InChI
1S/C9H10O2/c1-7(10)8-3-5-9(11-2)6-4-8/h3-6H,1-2H3
SMILES string
COc1ccc(cc1)C(C)=O
assay
99%
form
solid
bp
152-154 °C/26 mmHg (lit.)
mp
36-38 °C (lit.)
solubility
H2O: soluble 2.474 g/L at 20 °C
functional group
ketone
Quality Level
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Application
4′-Methoxyacetophenone was used to study ruthenium catalyzed step growth copolymerization of 4′-methoxyacetophenone with α,ω-dienes to yield copolymers. It was used to determine the activity of various ketones approved as food additives against Clostridium Botulinum spores and cells.
General description
4′-Methoxyacetophenone undergoes biocatalytic enantioselective reduction using immobilized Rhodotorula sp. AS2.2241 cells to yield (S)-1-(4-methoxyphenyl) ethanol in a hydrophilic ionic liquid-containing co-solvent system.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
280.4 °F - open cup
flash_point_c
138 °C - open cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Ruthenium catalyzed regioselective step-growth copolymerization of 4'-methoxyacetophenone, or 4'-phenoxyacetophenone and a, ?-dienes.
Guo H and Weber WP.
Polym. Bull., 35(3), 259-264 (1995)
Antibotulinal properties of selected aromatic and aliphatic ketones.
Bowles BL and Miller AJ.
Journal of Food Protection, 56(9), 795-800 (1993)
Wen-Yong Lou et al.
Journal of biotechnology, 143(3), 190-197 (2009-07-21)
The biocatalytic enantioselective reduction of 4'-methoxyacetophenone to (S)-1-(4-methoxyphenyl)ethanol was successfully conducted in a hydrophilic IL-containing co-solvent system using immobilized Rhodotorula sp. AS2.2241 cells. Of all the tested ILs, the best results were observed with the novel IL 1-(2'-hydroxy)ethyl-3-methylimidazolium nitrate (C(2)OHMIM.NO(3))
[Toxicological characteristics of acetylanisole].
M I Makaruk et al.
Gigiena i sanitariia, (4)(4), 86-87 (1985-04-01)
Sanja Ćavar et al.
Pharmaceutical biology, 48(2), 170-176 (2010-07-22)
Stachys menthifolia Vis. (Lamiaceae) is an endemic species from the Balkan Peninsula spread throughout Albania, Greece, Montenegro, and Croatia. This article presents the first investigation of the essential oil composition of this species from Croatia. Aerial parts of the plant
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