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Assay
98%
refractive index
n20/D 1.555 (lit.)
bp
215-216 °C (lit.)
density
1.27 g/mL at 25 °C (lit.)
SMILES string
ClCc1cccc(Cl)c1
InChI
1S/C7H6Cl2/c8-5-6-2-1-3-7(9)4-6/h1-4H,5H2
InChI key
DDGRAFHHXYIQQR-UHFFFAOYSA-N
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Application
3-Chlorobenzyl chloride has been used in the reaction of 3-methoxybenzyl chloride and ethyl 4-bromobenzoate in pure water, using zinc dust and a Pd catalyst.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
208.4 °F
Flash Point(C)
98 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Chemical communications (Cambridge, England), 46(4), 562-564 (2010-01-12)
A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide together in the presence of Zn metal and a Pd catalyst, diarylmethanes are
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